synthesis and molecular structures of two [1,4-bis(3-pyridyl)-2,3-diazo-1,3-butadiene]-dichloro-zn(ii) coordination polymers合成和分子结构的两个[1,4-bis(3-pyridyl)2,3-diazo-1,三丁基)-dichloro-zn(ii)协调聚合物.pdfVIP

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synthesis and molecular structures of two [1,4-bis(3-pyridyl)-2,3-diazo-1,3-butadiene]-dichloro-zn(ii) coordination polymers合成和分子结构的两个[1,4-bis(3-pyridyl)2,3-diazo-1,三丁基)-dichloro-zn(ii)协调聚合物.pdf

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synthesis and molecular structures of two [1,4-bis(3-pyridyl)-2,3-diazo-1,3-butadiene]-dichloro-zn(ii) coordination polymers合成和分子结构的两个[1,4-bis(3-pyridyl)2,3-diazo-1,三丁基)-dichloro-zn(ii)协调聚合物

Molecules 2006, 11, 589-596 molecules ISSN 1420-3049 Full Paper Synthesis and Molecular Structures of Two [1,4-bis(3-pyridyl)- 2,3-diazo-1,3-butadiene]-dichloro-Zn(II) Coordination Polymers Gene-Hsiang Lee † and Hsin-Ta Wang* Institute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan, ROC; † e-mail: ghlee@.tw * Author to whom correspondence should be addressed; e-mail: htwang@.tw Received: 5 June 2006; in revised form: 30 July 2006 / Accepted: 31 July 2006 / Published: 10 August 2006 Abstract: Two novel coordination polymers with 3D metal-organic frameworks (MOFs) have been synthesized by reacting 1,4-bis(3-pyridyl)-2,3-diazo-1,3-butadiene (L) with zinc dichloride. Both compounds have the same repeating unit consisting of a distorted tetrahedral Zn(II) center coordinated by two chlorides and two pyridyl nitrogen atoms of two bridging bismonodentate L ligands, however, different structural conformations have been found, one forming a helical chain and the other producing a square-wave chain. The intermolecular C−H···Cl hydrogen bonds in 1 and 2 play important roles in the formation of three-dimensional coordination polymers. Compound 1 crystallized in an orthorhombic space group Pna21 with a = 7.9652(3), b = 21.4716(7), c = 8.2491(3)Å, V = 1410.81(9) Å 3 and Z = 4. Compound 2 crystallized in a monoclinic space group P21/n with a = 9.1752(3), b = 14.5976(4), c = 10.3666(3) Å , β = 98.231(2)°, V = 1374.16(7) Å 3 and Z = 4. Keywords: Coordination Polymer, Metal-orga