原创力文档synthesis and nmr-study of the 2,3,4,5-tetraethylsilole dianion [sic4et4]2？？2[li]+合成和nmr-study的2、3、4,5-tetraethylsilole二阶阴离子(sic4et4)2 2(李)+.pdfVIP
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synthesisandnmr-studyofthe2,3,4,5-tetraethylsiloledianion[sic4et4]2？？2[li]合成和nmr-study的2、3、4,5-tetraethylsilole二阶阴离子(sic4et4)22(李)
Molecules 2011, 16, 8033-8040; doi:10.3390/molecule
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Communication
Synthesis and NMR-Study of the 2,3,4,5-Tetraethylsilole
Dianion [SiC Et ]2−•2[Li]+
4 4
Jang-Hwan Hong
Department of Nanopolymer Material Engineering, Pai Chai University, 155-40 Baejae-ro
(Doma-Dong), Seo-Gu, Daejon 302-735, Korea; E-Mail: jhong@pcu.ac.kr; Tel.: +82-42-520-5755;
Fax: +82-42-520-5798
Received: 31 August 2011; in revised form: 8 September 2011 / Accepted: 14 September 2011 /
Published: 16 September 2011
2− +
Abstract: The previously unknown silole dianion [SiC Et ] •2[Li] (3) was prepared by
4 4
the sonication of 1,1-dichloro-2,3,4,5-tetraethyl-1-silacyclopentadiene [Cl SiC Et , 2] with
2 4 4
more than four equivalent of lithium in THF. 1H-, 13C-, and 29Si-NMR data of 3 are
compared with those of the reported silole dianion [SiC Ph ]2−. Trapping of 3 with
4 4
trimethylchlorosilane gave 1,1-bis(trimethylsilyl)-2,3,4,5-tetraethyl-1-silacyclopentadiene
[(Me Si) SiC Et , 4] in high yield. The silole of 2 was synthesized in high yield in thre
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