synthesis of polypyrrole-intercalated grafted zirconium phosphate films by anodic electrodeposition and their electrochemical capacities合成polypyrrole-intercalated嫁接磷酸锆电影由阳极电沉积及其电化学的能力.pdfVIP

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synthesis of polypyrrole-intercalated grafted zirconium phosphate films by anodic electrodeposition and their electrochemical capacities合成polypyrrole-intercalated嫁接磷酸锆电影由阳极电沉积及其电化学的能力.pdf

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synthesis of polypyrrole-intercalated grafted zirconium phosphate films by anodic electrodeposition and their electrochemical capacities合成polypyrrole-intercalated嫁接磷酸锆电影由阳极电沉积及其电化学的能力

Polymers 2011, 3, 1-9; doi:10.3390/polym3010001 OPEN ACCESS polymers ISSN 2073-4360 /journal/polymers Article Synthesis of Polypyrrole-Intercalated Grafted Zirconium Phosphate Films by Anodic Electrodeposition and Their Electrochemical Capacities Takahiro Takei *, Qiang Dong, Yoshinori Yonesaki, Nobuhiro Kumada and Nobukazu Kinomura Center for Crystal Science and Technology, University of Yamanashi, 7-32 Miyamae, Kofu, Yamanashi 400-8511, Japan; E-Mails: dongqiang@yamanashi.ac.jp (Q.D.); yonesaki@yamanashi.ac.jp (Y.Y.); kumada@yamanashi.ac.jp (N.K.); kinomura@yamanashi.ac.jp (N.K.) * Author to whom correspondence should be addressed; E-Mail: takei@yamanashi.ac.jp; Tel.: +81-55-220-8616; Fax: +81-55-254-3035. Received: 4 November 2010; in revised form: 30 November 2010 / Accepted: 20 December 2010 / Published: 23 December 2010 Abstract: Ternary hybrid film composed of -zirconium phosphate nanosheet, 1,2-bis(dimethylchlorosilyl)ethane and polypyrrole was prepared by anodic electrodeposition. In the hybrid film, ordered -zirconium nanosheets with grafts by silylation lay down parallel to the substrate and the polypyrrole molecules were intercalated between the nanosheets. The electrochemical measurements confirmed that the hybrid film indicated capacitive behavior and the redox activity increase by approximately 25%. Keywords: electrodeposition; electrochemical capacitor; graft; polypyrrole; zirconium phosphate 1. Introduction The conductive