原创力文档synthesis of porphyrin-dendrimers with a pyrene in the periphery and their cubic nonlinear optical properties合成的porphyrin-dendrimers芘外围和立方非线性光学性质.pdfVIP
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synthesis of porphyrin-dendrimers with a pyrene in the periphery and their cubic nonlinear optical properties合成的porphyrin-dendrimers芘外围和立方非线性光学性质
Molecules 2011, 16, 6950-6968; doi:10.3390/molecule
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Article
Synthesis of Porphyrin-Dendrimers with a Pyrene in the
Periphery and Their Cubic Nonlinear Optical Properties
1 2 3
Eric G. Morales-Espinoza , Irina V. Lijanova , Omar G. Morales-Saavedra ,
Vícente Torres-Zuñiga 3, Simon Hernandez-Ortega 1 and Marcos Martínez-García 1,*
1 Instituto de Química, Universidad Nacional Autónoma de México, Cd. Universitaria,
Circuito Exterior, Coyoacán, C.P., México D.F. 04510, Mexico
2 Instituto Politécnico Nacional, CIITEC, Cerrada Cecati S/N, Colonia Santa Catarina de
Azcapotzalco, C.P., México D.F. 02250, Mexico
3 Centro de Ciencias Aplicadas y Desarrollo Tecnológico, Universidad Nacional Autónoma de
México, CCADET-UNAM, Circuito exterior S/N, Ciudad Universitaria C.P.,
México D.F. 04510, Mexico
* Author to whom correspondence should be addressed: E-Mail: margar@servidor.unam.mx.
Received: 9 June 2011; in revised form: 3 August 2011 / Accepted: 5 August 2011 /
Published: 15 August 2011
Abstract: Dendrons of pyrene derivatives were attached to a porphyrin core. A marked
effect in solution for the dendrimers was observed in the absorption spectra. All the
compounds obtained were characterized by 1H-, 13C-NMR, FTIR, UV-vis, MALDI-TOF or
FAB+ mass spectrometry and elemental analysis. The cubic nonlinear optical behavior of
some the synt
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