synthesis, properties characterization and applications of various organobismuth compounds各种organobismuth化合物的合成、性能表征和应用程序.pdfVIP
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synthesis, properties characterization and applications of various organobismuth compounds各种organobismuth化合物的合成、性能表征和应用程序
Molecules 2011, 16, 4191-4230; doi:10.3390/molecule
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Review
Synthesis, Properties Characterization and Applications of
Various Organobismuth Compounds
Jingfei Luan *, Lingyan Zhang and Zhitian Hu
State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment,
Nanjing University, Nanjing 210093, China; E-Mails: zhanglingyanyaner@163.com (L.Z.),
huzt123@126.com (Z.H.)
* Author to whom correspondence should be addressed; E-Mail: jfluan@;
Tel.: +86-135-8520-6718; Fax: +86-25-8370-7304.
Received: 15 April 2011; in revised form: 9 May 2011 / Accepted: 12 May 2011 /
Published: 20 May 2011
Abstract: Organobismuth chemistry was emphasized in this review article due to the low
price, low toxicity and low radioactivity characteristics of bismuth. As an environmentally-
friendly class of organometallic compounds, different types of organobismuth compounds
have been used in organic synthesis, catalysis, materials, etc. The synthesis and property
characterization of many organobismuth compounds had been summarized. This review
article also presented a survey of various applications of organobismuth compounds in
organic transformations, as reagents or catalysts. The reactivity, reaction pathways and
mechanisms of reactions with organobismuths were discussed. Less common and limiting
aspects of organobismuth compounds were also briefly mentioned.
Keywords: organobismuth compounds; synt
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