tetraazacyclohexadeca macrocyclic ligand as a neutral carrier in a cr ion-selective electrodetetraazacyclohexadeca大环配体作为一个中立的载体在铬离子选择性电极.pdfVIP

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tetraazacyclohexadeca macrocyclic ligand as a neutral carrier in a cr ion-selective electrodetetraazacyclohexadeca大环配体作为一个中立的载体在铬离子选择性电极.pdf

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tetraazacyclohexadeca macrocyclic ligand as a neutral carrier in a cr ion-selective electrodetetraazacyclohexadeca大环配体作为一个中立的载体在铬离子选择性电极

Sensors 2004, 4, 187-195 sensors ISSN 1424-8220 © 2004 by MDPI /sensors Tetraazacyclohexadeca Macrocyclic Ligand as a Neutral Carrier in a Cr Ion-selective Electrode Ashok Kumar Singh 1,*, Rupam Singh 1, Puja Saxena 1 1 Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee - 247 667, India * Author to whom correspondence should be addressed. E-mail: akscyfcy@iitr.ernet.in Received 15 April 2004 / Accepted 02 November 2004 / Published 22 December 2004 Abstract: A polystyrene-based membrane of 2,10-dimethyl-4,12-diphenyl-1,5,9,13- tetraazacyclohexadeca-1,4,9,12-tetraene macrocyclic ionophore was prepared and investigated as Cr(III)-selective electrode. The best performance was observed with the membrane having the polystyrene-ligand-dibutylphthalate-sodiumtetraphenyl borate composition 1:4:1:1 with a Nernstian slope of 19.0 mV per decade of concentration between pH 3.0 and 6.5. This electrode has been found to be chemically inert and of adequate stability with a response time of 20 s and was used over a period of 100 d with good reproducibility (S= 0.3 mV). The membrane works satisfactorily in a partially non-aqueous medium up to a maximum 30% (v/v) content of methanol and ethanol. The potentiometric selectivity coefficient values indicate that the membrane sensor is highly selective for Cr(III) ions over a number of monova