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the extension of statistical entropy analysis to chemical compounds扩展的统计熵分析化合物
Entropy 2012, 14, 2413-2426; doi:10.3390/
OPEN ACCESS
entropy
ISSN 1099-4300
/journal/entropy
Article
The Extension of Statistical Entropy Analysis to Chemical
Compounds
Alicja P. Sobańtka 1, Matthias Zessner 1,2 and Helmut Rechberger 1,2,*
1 Centre for Water Resource Systems, Vienna University of Technology, Karlsplatz 13/E222, A-1040
Vienna, Austria; E-Mail: sobantka@waterresources.at (A.P.S.)
2 Institute for Water Quality, Resource and Waste Management, Vienna University of Technology,
Karlsplatz 13/226, A-1040 Vienna, Austria; E-Mail: m.zessner@iwag.tuwien.ac.at (M.Z.)
* Author to whom correspondence should be addressed; E-Mail: helmut.rechberger@tuwien.ac.at;
Tel.: +43-1-58 801-226 45; Fax: +43-1-58 801-226 97.
Received: 23 August 2012; in revised form: 25 September 2012 / Accepted: 26 November 2012 /
Published: 28 November 2012
Abstract: Statistical entropy analysis (SEA) quantifies the dilution and concentration of
conservative substances (e.g., heavy metals) in a system. In this paper, the SEA concept is
extended (eSEA) to make it applicable to systems in which the chemical speciation is of
particular importance. The eSEA is applied to a simplified region used for crop farming.
The extent to which the region concentrates or dilutes nitrogen compounds is expressed as
the change in statistical entropy (H). A detailed derivation for the calculation of H is
provided. The results are discussed for four variations of the crop farming system, showing
that the efficiency of crop farming can
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