the first lanthanide telluride-bromide la3te4br, a valence compound第一个镧系元素telluride-bromide la3te4br,价化合物.pdfVIP
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the first lanthanide telluride-bromide la3te4br, a valence compound第一个镧系元素telluride-bromide la3te4br,价化合物
Crystals 2011, 1, 15-21; doi:10.3390/cryst1010015
OPEN ACCESS
crystals
ISSN 2073-4352
/journal/crystals
Article
The First Lanthanide Telluride-Bromide: La Te Br, a Valence
3 4
Compound
Markus Larres 1, Anja-Verena Mudring 2 and Gerd Meyer 1,*
1 Department für Chemie, Universität zu Köln, Greinstraße 6, D-50939 Köln, Germany;
E-Mail: larresm@uni-koeln.de
2 Fakultät für Chemie, Ruhr-Universität Bochum, D-44780 Bochum, Germany;
E-Mail: anja.mudring@rub.de
* Author to whom correspondence should be addressed; E-Mail: gerd.meyer@uni-koeln.de;
Tel.: +49-221-470-3262; Fax: +49-221-470-5083.
Received: 21 February 2011; in revised form: 10 March 2011 / Accepted: 18 March 2011 /
Published: 21 March 2011
Abstract: The first ternary lanthanide telluride-bromide La Te Br was obtained from a
3 4
mixture of LaTe and LaBr3 (in the presence of iridium) in a sealed tantalum container at
elevated temperatures. The crystal structure (orthorhombic, Pnma, a = 1634.3(2),
b = 435.0(1), c = 1426.6(2) pm, Z = 4, R (I 2(I )) = 0.0349) is built from dicapped
1 0 0
trigonal prisms of tellurium and bromine atoms surrounding lanthanum in two different
ways. The dicapped trigonal prisms are connected via common edges to a th
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