原创力文档the hildebrand solubility parameters of ionic liquids—part 2离子的希尔德布兰德溶解度参数liquids-part 2.pdfVIP
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the hildebrand solubility parameters of ionic liquids—part 2离子的希尔德布兰德溶解度参数liquids-part 2
Int. J. Mol. Sci. 2011, 12, 3553-3575; doi:10.3390/ijm
OPEN ACCESS
International Journal of
Molecular Sciences
ISSN 1422-0067
/journal/ijms
Article
The Hildebrand Solubility Parameters of Ionic Liquids—Part 2
Andrzej Marciniak
Department of Physical Chemistry, Faculty of Chemistry, Warsaw University of Technology,
Noakowskiego 3, 00-664 Warsaw, Poland; E-Mail: a.marciniak@.pl;
Tel.: +48-222-345-816; Fax: +48-226-282-741
Received: 6 April 2011; in revisedform: 19 May 2011 / Accepted: 26 May 2011 /
Published: 3 June 2011
Abstract: The Hildebrand solubility parameters have been calculated for eight ionic
liquids. Retention data from the inverse gas chromatography measurements of the activity
coefficients at infinite dilution were used for the calculation. From the solubility
parameters, the enthalpies of vaporization of ionic liquids were estimated. Results are
compared with solubility parameters estimated by different methods.
Keywords: ionic liquid; Hildebrand solubility parameter; enthalpy of vaporization
1. Introduction
Ionic liquids (ILs) are a relatively new class of salts with a melting temperature below 373.15 K. In
general, ILs are composed of organic cations with either inorganic or organic anions. Ionic liquids
have unique properties, namely, a wide liquid range, stability at high temperatures and negligible vapor
pressure. Because of th
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