临界区甲醇的聚碳酸酯降解研究-环境科学学报.PDFVIP

24 1 Vol. 24, No. 1 2004 1 ACTA SCIENT IAE CIRCUMSTANTIAE Jan. , 2004 : 2004) : X132 : A 陈 磊, 吴勇强, 倪燕慧, 黄 科, 朱子彬 ( , 200237) : . , 220 260 , 520 867 MPa , 5 45 min, GCMS GCFID , ( DMC) A ( BPA) . 240 30 min , DMC BPA 9 175% 9003% . ( GPC) 240 . , , PC ( M n) , DMC BPA , , DMC BPA , PC . : Depolymerization of polycarbonate in critical region of methanol CHEN Lei, WU Yongqiang, NI Yanhui, HUANG Ke, ZHU Zibin ( Research Institut e of Chemical T echnology , East Chi na University of Science and Technology , Shanghai 200237) Abstract: Depolymerizat ion of polycarbonate in crit ical region of methanol was studied in absence of cataly sts and in a batchtype autoclave at react ion temperat ure of 220 260 and with react ion time of 5 45 min. The main liquid productsw ere demethyl carbonat ( DMC) and bis phenolA( BPA) , which were ident if ied and quantified by GCMS and GCFID. In crit ical region of methanol at 240 for reaction time of 30 min, the yield of DMC and BPA reached 9 175% and 9003% , respect ively. Gel Permeation Chromatography was used to measure the num beraverage molecular weight ( Mn ) of solid products. Based on the experiments, mechanism of methanolysis was proposed in this paper . Keywords: polycarbonate methanol critical region depolymerizat ion mechanism 2000 10350 kt , 175000 kt[ 1] . , , 50% . [ 2] . , . ( PC) , , 1999 PC 1930 kt, 2002 2300 kt . PC , , . [ 2] [ 3, 4] PC , PC Suzuki PC BPA Oku NaOH , PC BPA[ 5] Hu[ 6] , NaOH PC . , , [ 7] , . T akeshi