环氧-丙烯酸树脂乳液性能与涂膜固化规律的研究.PDFVIP

环氧-丙烯酸树脂乳液性能与涂膜固化规律的研究 孙培勤 杨勋兰 孙绍晖 刘大壮 郑州大学化工学院，郑州 450002 关键词：环氧树脂，丙烯酸，乳液，粘度，固化 环氧树脂具有优异的粘合性、防腐性和力学性能，是重要的塑料、涂料、粘 合剂、复合材料用树脂。常用环氧树脂为非水溶性的，只溶于酮类、醚醇类等有 机溶剂，有机溶剂的挥发污染环境，危害人类健康。随着对环境保护的要求日益 严格，环氧树脂水性化的研究具有重要意义。采用丙烯酸接枝改性环氧树脂的方 法可制得自乳化自交联型的乳液，涂膜既具有环氧树脂的高模量、高强度、耐化 学品和优良防腐性，又兼具丙烯酸树脂光泽、丰满度、耐侯性好等特点。本文在 研究聚合反应规律，获得优化的工艺配方的基础上，考察环氧－丙烯酸树脂乳液 的性能和涂膜的固化规律。针对乳液在涂料应用中的重要性能，考察了乳液粘度 随固含量、温度、和pH 值的变化规律。通过测定涂膜吸水率、交联率，得到了 涂膜的固化规律，并用红外光谱分析了涂膜的固化反应机理。结果表明：制得的 涂膜耐水性、附着力、柔韧性和防腐等性能优异。 Study on the performance of Epoxy-Acrylate Emulsion Sun Peiqin Yang Xunlan Sun Shaohui Liu Dazhuang College of Chemical Engineering, Zhengzhou University, Zhengzhou, 450002 Key words: epoxy resin, acrylic, emulsion, viscosity, curing Epoxy resin is widely used in the field of anticorrosive coating industry because of its high adhesive and good chemical resistant. But epoxy resin is indissolvable in water, only dissolvable in organic solvent. Epoxy resin can be modified by acrylic acid, then be neutralized to water dispersion. It accommodates coating industry’s requirement of saving resources and protecting environment. Self-emulsified and self-cross linked epoxy-acrylate emulsion was prepared by graft copolymerization. The emulsion viscosity changing with the solid content ，temperture and pH was obtained. The curing rule of coating film was obtained by testing the water absorption and cross linked rate. The curing reaction principle was attributed by infer-red spectrum. The results indicated that the cured coating film was excellent in water resistance, adhesion, flexibility and corrosion resistance 1 前言 环氧树脂具有优异的粘合性、防腐性和力学性能，是重要的塑料、涂料、粘 合剂、复合材料用树脂。常用环氧树脂为非水溶性的，只溶于酮类、醚醇类等有 机溶剂，有机溶剂的挥发污染环境，危害人类健康。随着对环境保护的要求日益 严格，环氧树脂水性化的研究越来越受到重视 [1~3] 。采用丙烯酸接枝改性环氧树 脂的方法可制得自乳化自交