环糊精介导聚苯乙烯微球的制备及表征.PDFVIP

第26 卷第3 期 湖 南 工 业 大 学 学 报 Vol.26 No.3 20 12 年5 月 Journal of Hunan University of Technology May 20 12 doi :10.3969/j .issn.1673-9833.20 12.03.006 环糊精介导聚苯乙烯微球的制备及表征 王 玮，邓 燕，何农跃 （湖南工业大学绿色包装与生物纳米技术应用重点实验室，湖南 株洲 4 12007 ） 摘 要：选用β-环糊精为稳定剂，以苯乙烯为原料、过硫酸钾为引发剂，采用无皂乳液聚合法制备单 分散聚苯乙烯微球。利用扫描电镜对微球进行表征，研究了微球合成过程中稳定剂用量、苯乙烯单体用量 及引发剂用量对微球粒径分布的影响。实验结果表明：适当地改变稳定剂用量、苯乙烯单体用量及引发剂 用量可以得到不同粒径且单分散性良好的聚苯乙烯微球。 关键词：苯乙烯；β-环糊精；无皂乳液聚合；聚苯乙烯 中图分类号：TQ317.2 文献标志码：A 文章编号：1673-9833(2012)03-0025-04 Preparation and Characterization of Cyclodextrin-Mediated Polystyrene Microspheres Wang Wei ，Deng Yan ，He Nongyue （Key Laboratory of Green Packaging and Application of Biological Nanotechnology ， Hunan University of Technology ，Zhuzhou Hunan 4 12007 ，China ） Abstract ：Using styrene as raw material, potassium persulfate as an initiator and -cyclodextrin as a stabilizer, β polystyrene microspheres were successfully prepared by means of soap-free emulsion polymerization method. The micro- structures were characterized with SEM, and the effects of the stabilizer dosage, the styrene monomer dosage and initiator dosage on the particle size distribution were studied. The results show that polystyrene microspheres with different particle sizes and good monodispersity were obtained by changing amount of stabilizer and the styrene monomer dosage and dosage of initiator appropriately. Keywords ：styrene ； -cyclodextrin ；soap-free emulsion polymerization ；polystyrene β [8] 0 引言