第3讲 高分子链的柔性和溶液热力学1015F.pptVIP

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * 溶解过程 The solution process (linear Polymer) This process is usually slower compared with small molecules, and strongly dependent on the chemical structures and condensed states of the samples. * Swelled Sample Polymer Solution 高分子特点：先溶胀，后溶解 Crosslinked polymers: only can be swelled 交联高分子：有溶胀，无溶解 Crystalline polymers 结晶高分子：先熔融，后溶解 Crystalline PE: dissolve at the temperature approached to its melting temperature. Crystalline Nylon 6,6: