PPS复合材料射压成型成品导电性之研究李平惠机械工程系摘要燃料.PDFVIP

教專研 101P-008 PPS複合材料射壓成型成品導電性之研究 PPS複合材料射壓成型成品導電性之研究 李平惠 機械工程系 摘要 燃料電池(Fuel Cell)是一種對地球生態污染性較低且發電效率較高的能源，而雙極板 (Bipolar Plate)佔據全部電池大半主體，是燃料電池的主要 元件。以高分子導電性複合材 料成型之雙極板，具有重量輕、抗腐蝕佳、成本低、加工快的優點，若能於導電度上有 所突破，就能逐漸取代石墨或金屬雙極板。本研究主要是選取 PPS 複合高分子材料，藉 由改變不同流道配置的方向 (進澆口平行/ 垂直流道方向) ，探討傳統射出成型與射出壓縮 成型製作燃料電池雙極板製程中，對碳纖維配向、分佈與導電性之影響。 研究結果顯示，利用 PPS 基材添加 20wt.%GP ，以模溫210℃、料溫330℃、射速 60mm/s 、保壓 150MPa 、開模間距 0.8mm 之製程參數射出壓縮成型後，平面導電度為 156S/cm(達到國際 DOE 之標準) ，流道配置垂直充填方向以射出壓縮成型，平面導電度 提升至 183S/cm ，達到本研究目的之要求。 關鍵字： 雙極板、碳纖維、配向 Abstract Fuel cells constitute one of the most promising sources of clean energy and bipolar plate is an important component of a fuel cell. Electrically conductive polymer composites for molding of bipolar plates, has the advantages of lightweight, low cost, chemical stability, and ease of fabrication. They will can alternative to graphite and metal-based material if one can improve the conductivity of polymer composite. In this study, bipolar plates without channel were injection molding (IM) and injection-compression molding (ICM) using PPS polymer filled with 50 wt% carbon fiber and different content of graphite under different molding parameters was addressed. The effect of processing parameters including mold temperature, melt temperature, injection velocity, and packing pressure on the electrical conductivity performance were analyzed and correlated. Meanwhile, influence of fiber orientation and distribution from molding conditions was evaluated. The results showed that when the molding condition was chosen (mold temperature 210