质谱（mass spectrum）.docVIP

质谱（mass spectrum） Mass spectrometry (MS), 2010-05-22, 22:597.4.1 principle Mass spectrometry is one of the important methods to determine the structure of organic compounds developed in the 40s of this century. The mass spectrometer mainly consists of four parts Ionization variable arc magnetic field ion collector recorder In mass spectrometry, the sample is converted to vapor in the ionization chamber. The ionization chamber is a high vacuum (10-8 mmHg), an electron source in the ionization chamber, the electron beam can emit high energy, organic compounds by high-energy electron beam bombardment, they can lose an outer electrons into high molecular ions with positive charge on a. M + e, M+ + 2e These energetic molecules can also be cleaved into a variety of positively charged cations, negatively charged anions, and uncharged fragments. There is also an accelerator in the ionization chamber, where the positive ions can be accelerated and enter the strong magnetic field below, while the negative ions and neutral fragments are not accelerated and evacuated by vacuum pumps. The magnetic field in mass spectrometry is an arc magnetic field, which enters a positive ion in a strong magnetic field. Because of their different mass of m/z, when they are moving along the arc track, m/z is different Ions vary in degrees of curvature. When the positive ion acts as an arc, the centripetal force (Hen) is balanced with the centrifugal force mv2/R. H is the magnetic field intensity, and R is the radius of curvature of the ion motion. E, m and V are the charge, mass and velocity of ion motion, respectively. Since the ion is accelerated in an electric field whose electric field is V, its kinetic energy is equal to that of potential energy: Combine the above two formula to get: Cationic mass small, arc radius is small, and large mass cation, arc radius, so, according to the detected signal, you can know the quality of debris, that is to say, which is split into compound ions, accordin