铝酸钠溶液离子膜电解方法制备氢氧化铝-中南大学学报.pdfVIP

第 38 卷第 1 期 中南大学学报( 自然科学版) Vol.38 No.1 2007 年 2 月 J. Cent. South Univ. (Science and Technology) Feb. 2007 铝酸钠溶液离子膜电解方法制备氢氧化铝 1，2 1 1 1 1 1 陶 涛 ，陈启元 ，李元高 ，郭春平 ，尹周澜 ，张平民 (1. 中南大学 化学化工学院，湖南 长沙，410083； 2. 宁夏大学 天然气转化自治区重点实验室，宁夏 银川，750021) 摘要：对中等浓度的铝酸钠溶液，利用离子膜技术对其进行电解种分，所得产品用 X 射线检测。研究结果表明： 铝酸钠溶液通过离子膜电解种分，不但可获得纯度较高氢氧化铝产品，还可获得浓度较高的 NaOH 溶液和副产物 H 与 O ；通电约 12 h 后，分解率可达 71.7% ；离子膜电解种分的分解率明显高于拜耳法种分的分解率。 2 2 关键词：离子膜；电解；铝酸钠溶液 中图分类号：O614.3 ；TQ151 文献标识码：A 文章编号：1672-7207(2007)01−0102−05 Production of Al(OH) by ion membrane electrolysis 3 in sodium aluminate solution 1,2 1 1 1 1 1 TAO Tao , CHEN Qi-yuan , LI Yuan-gao , GUO Chun-ping , YIN Zhou-lan , ZHANG Ping-min (1. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China; 2. Ningxia Key Laboratory of Natural Gas Conversion, Ningxia University, Yinchuan 750021, China) Abstract: The sodium aluminate solution of medium-concentration was electrolyzed by using ion membrane in a specially designed cell and then was precipitated in seeds cell. The product obtained was determined by X-ray diffraction. The results show that Al(OH)3 solid product and NaOH solution of cathode with the higher concentration could be as well as the by products H and O obtained. It takes 12 h for the sodium aluminate solution to electrolyze and precipitate, and 2 2 the p