染料及表面活性剂的太阳光催化降解 - 天津大学期刊中心.pdfVIP

36 1 　　　　　 Vol.36　No.1 　　200　3 1 Journal of Tianjin Uni ersity Jan.2003 　 1 1 2 3 张天永, 张友兰, 赵进才, 日高 久夫 (1., 300072;2., 100080; 3., 191—8506) 　:制作了一种聚集太阳光光催化反应装置, 在纳米半导体TiO 存在下可用于净化染料和 面活性剂污染物, 2 并可使其快速降解并矿化.含有N— 甲基助色基团染料的降解伴随脱甲基过程, 混合物最大吸收峰发生蓝移.总有 机碳(TOC)值降低与污染物有关, 当降解生成中间体与污染物有较强的竞争吸附时, TOC 值有升高现象.对不同的 污染物降解, 有不同的较适宜的TiO 用量. 2 :;;;;; :O643;X7　　　:A　　　:0493-2137(2003)01-0005-04 Photocatalytic Decomposition of Dyes and Surfactant Under Solar Light Irradiation ZHANG Tian-yong, ZHANG You-lan, ZHAO Jin-cai, HI AKA Hisao (1.School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; 2.Institute of Chemistry, the Chinese Academy of Sciences, Beijing 100080, China; 3.Frontier Research Center for the Global Environmental Protection, Meisei University, Tokyo 191-8506, Japan) Abstract:A solar light concentratorfor photocatalytic reactionwasprepared, withwhich dyesandsurfactant pollutants could be efficiently degraded andmineralized.Accompaniedwithmineralization, N—demethylationof dyes containing N—methyl groupsoccurred, andmade the maximal absorption bandof degradedmixtureshypsochromic effects.Elim- ination of total organic carbon (TOC)is related to the properties of pollutants degraded.The strong competitive ad- sorption between the pollutantsand the formed intermediateslead to the temporalTOC increase.VariousoptimalTiO2 loadings is corresponded to the different substrates decomposed. Keywords:photocatalysis;solar light;tita