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ABSTRACT
Semi-insulating Gallium Arsenic (SI-GaAs) is a kind of semiconductor with
semi-insulating properties, higher mobility , direct and wide band-gap. The
semiconductor devices made by gallium arsenide have the characteristics of
thermostable, low noise, high speed, high frequency, higher radiation hardness etc,
and is an exensive application in high-tech field such as communication device, night
vision technology and detector. With the progress of nuclear and space technology,
demand is increasing for the semiconductor devices used in the radiation environment.
In current commercial SI-GaAs crystal growth process, Liquid Encapsulated
Czochralski (LEC) method and Vertival Gradient Freeze (VGF) method are major
technology. Therefore, the investigation on radiation characteristics of LEC and VGF
SI-GaAs is of great application value.
In this paper, we mainly focus on the structural and electrical properties in large
diameter LEC and VGF SI-GaAs after electron irradiation. The patterns of defects
were investigated by means of ultrasonic AB etching, metallurgical microscope and
infared technique in as-grown LEC and VGF SI-GaAs, and different patterns of
dislocations and micro-defects were observed. The concentration and radial
distribution of EL2 defect and impurity C are characterized by Fourier transform
infrared spectroscopy (FTIR). The structure properties induced by electron irradiation
were studied by Raman spectra. And the influence of irradiation and anne
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