Iminophosphines亚胺膦配体.pdf

Journal of Organometallic Chemistry 650 (2002) 231–248 /locate/jorganchem Iminophosphines: synthesis, formation of 2,3-dihydro-1H -benzo[1,3]azaphosphol-3-ium salts and N -(pyridin-2-yl)-2-diphenylphosphinoylaniline, coordination chemistry and applications in platinum group catalyzed Suzuki coupling reactions and hydrosilylations Simon Doherty a,*, Julian G. Knight b, Tom H. Scanlan b, Mark R.J. Elsegood b,1, William Clegg b a School of Chemistry, Daid Keir Building, The Queen’s Uniersity of Belfast, Stranmillis Road, Belfast BT9 5AG, UK b Department of Chemistry, Bedson Building, The Uniersity of Newcastle upon Tyne, Newcastle upon Tyne NE 1 7RU, UK Received 6 December 2001; accepted 11 January 2002 Abstract The aprotic and protic bi- and multidentate iminophosphines 2-Ph 1 2 1 2 1 2 PC H NCR R (R =H, R =Ph =2a; R =Me R = 2 6 4 Ph =2b; R1 =H, R2 =2-thienyl =2c; R1 =H, R2 =C H -2-PPh =2d; R1 =H, R2 =C H -2-OH =2e, R1 =H, R2 =C H -2-OH- 6 4 2 6 4 6 4 3-But =2f; R1 =H, R2 =CH C(O)Me =2g) have been prepared by the acid catalyzed condensation of