低温等离子体协同钒钛催化剂降解甲苯试验-北京工业大学学报.PDF

第41卷 第4期 北 京 工 业 大 学 学 报 Vol.41 No.4 2015年 4月 JOURNAL OF BEIJING UNIVERSITY OFTECHNOLOGY Apr. 2015 低温等离子体协同钒钛催化剂降解甲苯试验 梁文俊,王爱华,樊摇 星,孙翰林,李摇 坚,何摇 洪 (北京工业大学 环境与能源工程学院,北京摇 100124) 摘摇 要:采用可调频高压电源、自制线管式介质阻挡放电反应器,以挥发性有机化合物(VOCs)代表物质———甲苯 为去除对象,考察了低温等离子体协同不同类型催化剂降解甲苯性能. 对反应器能量密度、能量效率、副产物臭氧 生成情况进行了考查比较. 筛选出性能较优的催化剂,对其进行了稳定性实验,并对反应产物进行了测定分析. 研 究结果表明:填充钒钛系催化剂对甲苯的降解有明显的促进作用,能量密度和臭氧生成量有所降低,能量效率有明 显提高. 针对V O 鄄TiO/ 酌鄄Al O 催化剂进行的稳定性实验研究表明:甲苯去除率随反应时间延长而缓慢下降,表 2 5 2 2 3 明催化剂存在失活现象,可能是由甲苯降解形成的副产物在催化剂表面积聚而覆盖催化剂反应活性位造成的. 500 益空气气氛下焙烧4h能使催化剂的活性恢复至初始水平. 关键词:甲苯;低温等离子体;钒钛系催化剂;能量效率;臭氧 中图分类号:X701 文献标志码:A 文章编号:0254-0037(2015)04-0628-08 doi:10.11936/ bjutxb2014070022 Removal of Toluene by Non鄄thermal Plasma Coupled With V鄄Ti Catalysis LIANG Wen鄄jun,WANG Ai鄄hua,FAN Xing,SUN Han鄄lin,LI Jian,HE Hong (College of Environmental and Energy Engineering,Beijing University of Technology,Beijing 10024,China) Abstract:Removal of toluene by the combination of non鄄thermal plasma (NTP) and various catalysts was investigated in this study. Self鄄made wire鄄cylinder dielectric barrier discharge (DBD) reactor energized by AC power supply was used in our experiment. Specific energy density (SED), energy efficiency (EY) and O concentration of different reactor were investigated. The better catalyst was 3 chosen,catalyst stability test was carried out,and the by鄄products in the reaction were determined and analyzed. The results show that compared with 酌鄄Al O ,V O 鄄TiO/ 酌鄄Al O catalysts can enhance the 2 3 2 5 2 2 3 conversion of to