相成分与相变应力-中国科技论文在线.pdf

第34卷 第5期 仓 属学故 Vol_34 No．5 1 9 9 8年 5月 ACTA METALLURGICA SINICA M吖 1 9 9 8 组织的相成分与相变应力 ／ 王继杰 宗亚平 秦高梧 郝士明 ——面 葬雨 群院，沈阳11000s) 摘 要 应用X射线衍射测定了过饱和a2单相的Ti 45％Al舍囊在950℃等温分解过程中，初 生片层形成时的 相转变分数及 2和 相晶格参数的变化 结果表明，韧生片层中a2相是亚稳相， 其成分可 由自由能成分曲线的亚稳志a2相与 相自由能成分曲线公切线的切点确定，该成分的确定 对定量计算合金自由能及发生不连续粗化的转变驱动力有十分重要的作用：等温分解过程中原 晶粒内 部将产生相变应力、在垂直于初生片屡的方向上可 产生约50 MPa的压应力 谤应力将对合金的组织 形态有显著的影响 关键词 Ti Al合金．初生片层、相成分，相变应力 中图法分类号 TG146 2 PHASE CoMPoSITIoN AND TRANSF0RM r10N STRESS 0F PRIM ARY LAMELLAR STRUCTURE IN ，Y—TiAl—BASED DUPLEX ALLOY DURING ISoTHERMAL DEC0MPoSITIoN WANG Jijie．ZONG Yaping,QIN Gaowu,HAG Shiming School of M~teriais and Metallurgy,Northeastern University，Shenyang 110006 Correspondent：WANG Jifie，lecturer,Tel：(02~)3893000--7737 Man uscript received 1997-09·1i，in revised form 1997-12·i0 ABSTRACT During isothermal decomposition of the supersaturated a2 pha~e in Ti-45％A1 alloy at 950℃． the volume firactions of the decomposed 1 phase and the lattice parameters of both a2 and 1 phases have been investigated by X-ray diffraction．The results show that a2 phase in the primary lamellar microstructure fPLMS)is a metastable phase，and its composition should be identified by the tangency point on the conlmon tangent of metastable a2 and phase free--energy curves．T s composition is very important in calculation of free energy of the aⅡ0y and the driving force of discontinuous coarsening fDC)．There exists transformation stress inside the origi a grains at the direction perpendicular to PLMS Which is a COrnpress stress of about 印 MPa and will greatly affect the microstructure of the alloy． KEY W ORDS Ti—Al alloy,primary lamellar structure phase composition