Cr2O3对掺锶亚锰酸镧非化学整比晶体结构电导率和热膨胀性能影响.PDFVIP

/ 199711 Cr2O3 Effect of Doping Cr2 O3 on Nonstoichiometry, Crystal Structure, Conduc- tivity and T hermal Expansion roperty of ( La0. 85 Sr0. 15) MnO3+ D for SOFC ( ) ( , ) Yang Wei Sui Zhitong School of Materials and Metallurgy Northestern U niversity [ ] Cr O ( Cr Mn) ( La Sr ) MnO 2 3 0.85 0.15 3 Mn4+ : [ Mn4+ ] / [ M n+ Cr] , [ 4+ ] / [ 3+ ] ; D Cr Mn Mn Mn 10 00 , ( ) ; , D Cr Mn 1000 ( La, Sr) MnO3; YSZ [Abs tract] ( La, Sr) M nO3 doped with Cr2 O3 , a new cathode materials for SOFC, w as synthe- sized by pow der sintering in air to substitute Mn in the formula. The compounds ( La0. 85 Sr0. 15 ) ( Mn1-y Cry ) O3+ D , with y= 0, 0. 05, 0. 1, 0. 15 and 0. 2 w ere investigated on nonstoichiometry, crystal structure, electrical conductivity and thermal expansion coefficient. While increasing y, the molar ra- 4+ 4+ tio [ Mn ] / [ Mn + Cr] and oxide nonstoichiometry D decrease but the molar ratio [ Mn ] / 3+ [ Mn ] is constant , and that the conductivity tends to close at 1000 although the conductive acti- vation energy Ea increases In the sight of the experiment the crystal structure is rhombohedral and. , the thermal expansion coefficient is always compatible betw een the cathode materials and the solid electrolyte YSZ. Keywords SOFC lantanum manganite nonstoichiometry conductivity thermal expansion