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材料物理与性能知识点(Material physics and performance knowledge)
材料物理与性能知识点(Material physics and performance knowledge)
Maybe youre going to be worried about the review of the material physics and performance. Look at the summary. Its like a question bank. No, its a question bank! Put it in a mobile phone, as e-books, hehe ~ ~ ~ ~ ~ you are wrong, is to let you see before you go to bed. Personally think that in the mobile phone to see than the book on the effect of good, the editor has experience. Well, everyones getting into the review phase: OK, lets, go!!!
Chapter 1 Thermal Properties of materials
1. The thermodynamic theory of heat capacity of gas molecules is applied directly to solids, and the law of Dus substitution (the law of heat capacity of elements) is proposed. In fact, the atomic heat capacity of most elements is close to that value, especially at high temperatures.
2. Universal law:
The molecular heat capacity of a compound is equal to the sum of the atomic heat capacity of each element in the compound
3. Plancks basic point of view: the thermal vibration of a particle is of variable size, that is, the kinetic energy size is not fixed, but the energy is quantized.
1) Einstein heat capacity model:
Basic point of view: the vibration of an atom is independent and independent of each other; with the same surrounding environment, the vibrational frequencies are the same; the energy of vibration is discontinuous and quantized.
Conclusion:
At high temperature, Cv=3R coincides with the equation of Dulong and amber.
The tendency of Cv to change with T agrees with the experimental results at low temperature, but is approaching zero faster than the experiment.
When T = 0K, Cv also approaches 0, which agrees with the experimental results.
2) Debye specific heat model
Basic idea: atoms in a crystal interact with each other and the crystal is approximated as a continuous medium.
Since the main contribution to heat capacity in a lattice is the vibration of an elastic wave, the acoustic wave is longer than the lattice constant of
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