第七、八章 沉淀与重量法答案（The seventh, eighth chapter precipitation and weight method answer）.docVIP

第七、八章 沉淀与重量法答案（The seventh, eighth chapter precipitation and weight method answer） The seventh, eighth chapter precipitation and weight method answer: Fill in the blanks 1. K2CrO4; 2. 6.5~10.5; 4. 3.6.5-7.2; 5. NH4SCN; 6. iron alum; adsorption indicator; 7. from white to red brick; 8. reduced 9. increase; 10. increase; 11. smaller; 12.; 13. more _; 14._ is smaller; 15. Ag, Br-, AgI, AgSCN, precipitation conversion. 16. measuring points, measuring point in advance by ag. 17. Ag + negative. 18. heat up to boiling nitrobenzene. 19., Cl-, Br-, I-, SCN-, AgI are strongly adsorbed on I-, and AgSCN is strongly adsorbed on SCN- and can not be resolved by oscillation 20., colloidal precipitation, poly precipitation, adsorption. Two, multiple-choice questions 1. (ABC) (2). D (3). E (4). C (5). D (6). D 2.C, 3.D, 4.B, 5.C, 6.D, 7.C, 8.C, 9.A, 10.A,, 11.D, 12.C, 13.C Three. Calculation questions 1. answer: weighing form, measured components, conversion factors AI2O3 Al 2Al/AI2O3 BaSO4 (NH4), 2Fe (SO4), 6H2O (NH4), 2Fe (SO4), 6H2O, /2BaSO4 Fe2O3 Fe3O4 2Fe3O4/3Fe2O3 2. solutions: Ag++SCN-=AgSCN titration reaction: When measuring points, n (Ag+), =m (Ag+), /M (Ag+) N (Ag+), =CV (NH4SCN), M (Ag+) N (SCN-) =CV (NH4SCN) * m (Ag+) =CV (NH4SCN) - M (Ag+) Ag% = EMBED, Equation.3, EMBED, Equation.3 = EMBED Equation.3 = 6.15 3. solution: BaSO4 is crystal form precipitation, in the gravimetric method generally stipulates crystal precipitation, the residue obtained is 0.2 ~ 0.5g. To obtain BaSO4 precipitation for 0.5g, we need to sample xg: M INCLUDEPICTURE /fxhx/img1/xbmx.gif MERGEFORMATINET the =322.2 /fxhx/img1/xbbaso.gif; M INCLUDEPICTURE the MERGEFORMATINET =233.4 0.5 x 322.2/233.4=0.6902 0.6902/x=90%, x=0.8g 4. solutions: titration reaction: KCl+AgNO3=AgCl: +KNO3 KBr+AgNO3=AgBr: +KNO3 L measurement point: n (KCl)) +n (KBr) =n (AgNO3) Namely: EMBED Equation.3 EMBED Equation.3 EMBED Equation.3 Solution: m (KCl) =0.1071g * m (KBr) =0.2003g * KCl%= * 100=34.84 (0.1071/0.3074) KBr%= (0.200