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有机物的命名方法(Nomenclature of organic compounds)
有机物的命名方法(Nomenclature of organic compounds)
Nomenclature of organic matter
The naming method of organic nomenclature, habit of nomenclature, some organic matter and name.
First, the systematic nomenclature (IUPAC)
IUPAC nomenclature of organic compounds is a systematic nomenclature of organic compounds. The nomenclature was established by the International Union of pure and Applied Chemistry (IUPAC), and the most recent revision was in 1993. Its predecessor was the systematic nomenclature of the Geneva International Chemistry Society in 1892. Ideally, each organic compound with a clear structural formula can be described with a definite name. It is not strictly systematic nomenclature because it accepts the common naming of some substances and groups at the same time.
The systematic nomenclature of Chinese is based on the English IUPAC nomenclature in Chinese Chemistry Society and combines the characteristics of Chinese characters. Established in 1960, 1980 was revised according to the 1979 edition of English.
1: general rules
Sequence rules of substituents
When there are many substituents on the backbone, the order of the groups in the name is determined by the order rule. The general rule is..:
The higher the mass of the first atom of the 1. substituent, the higher the order;
If the first 2. atoms of the same, then compare their first atomic connected atomic order; if there is a double or triple bond, is connected to 2 or 3 of the same atom
The highest order functional group is used as the main functional group, and the name is placed at the end. Other functional groups, name the lower order, name the front.
Selection of main chain or main ring
Nomenclature of benzene derivatives with benzene as precursor, branched chain substituents, the naming of substituents on benzene words in front of the position of the substituent represented by the digital Arabia in branched chain is more important, can also be benzene ring as a substituent, with branched chain as the pare
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