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有机化学第二章答案(Second chapters of Organic Chemistry)
有机化学第二章答案(Second chapters of Organic Chemistry)
The second chapter is aliphatic hydrocarbon
Thinking and Practice
2-1 what is the difference between the same series and homologues? Are the two structural isomers of butane homologues?
The same series and homologues have different meanings. A series is a generic term for a series of compounds having the same general formula, similar structures, and one or more CH2 groups in composition. Homologues are specific compounds in the same series. For example, alkanes are the same series, and methane and ethane in alkanes are called homologues. The two structural isomers of butane are not homologues.
2-2 what methods and steps should be adopted for deducing the isomers of alkanes? Write out all the structural isomers of C6H14.
In the derivation of structural isomers of alkanes, the key of carbon chain isomerism should be seized. First, write the longest carbon chain that conforms to the molecular formula, and then reduce the longest carbon chain in turn (as the main chain). The less carbon atoms are attached to the main chain carbon atoms as branched chains. For example, C6H14 has the following 5 structural isomers.
What is the meaning of 2-3 aliphatic hydrocarbons? What kind of hydrocarbons does it contain? Write their general formulas, respectively.
Aliphatic hydrocarbon alicyclic hydrocarbons and fat covering.
2-4 point out which of the following compounds are homologues Which are isomers? Which are the same compounds?
: 1 and 8; homologues of the branch and the
Isomers: 1 and 6 and 7 4;
The same compound: and the
2-5 write the structure of the following hydrocarbons or hydrocarbons.
1 (CH3) 3C - CH3CH=CH - CH2=CHCH2 -
It is.
10, 30
2-6 name the following alkanes and mark the primary, secondary, tertiary, and quaternary carbon atoms of the following alkane molecules at 1, 2, 3, 4 degrees.
2,5- two methyl -3,4- two ethyl hexane 2,2,3- three methyl butane
2,4- two methyl hexane 2,2,10- three methyl -9- ethyl eleven alkane
2-
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