工业分析实验步骤（Industrial analysis experimental procedure）.docVIP

工业分析实验步骤（Industrial analysis experimental procedure） (I) EDTA complexing Reagent: (1) 1:1 ammonia solution; (2) 1:1 hydrochloric acid solution (3) 1:3 nitric acid solution (4) 10% sulfo salicylic acid solution (5) 0.02M EDTA standard solution (calibration) Determination procedure Accurately remove the sample solution 25mL (depending on the amount of iron) in the 250mL cone flask, plus 1:3 nitric acid 1mL. The solution PH was adjusted by 1:1 ammonia water and 1:1 hydrochloric acid, and the precision PH test paper was used to test 1.6~1.8. Heat to 60~70 degrees C, add 10% sodium salicylate solution 10 drops, while hot to 0.02M EDTA standard solution titration to yellow or light yellow. The percent content of ferric oxide by the following formula: Type M - the molar concentration of EDTA standard solution V - Titrimetric consumption of EDTA standard solution volume. ML G - sample weight, G (two) salicylic acid colorimetry reagent (1) 1:1 ammonia solution; (2) 10% sulfo salicylic acid solution (3) iron standard solution: weigh high iron alum 0.302g in a 500m volumetric flask, add 6N sulfuric acid 5mL, dissolved, diluted with water to the scale, shake. The solution containing 1mL per 0.1mg of ferric oxide. Determination procedure Accurate shift from sample solution 10.00mL in a 100mL volumetric flask, dilute with water to about 50mL, sulfosalicylic acid solution of 10mL10%, adding 1:1 to the solution of ammonia from red to yellow, then the excess 2~4mL, diluted with water to mix with 1cm, marking the cuvette, the absorbance of the Yu Bo 430mm. Standard curve: 0, 0.50, 1 respectively from 3, 5, 7, 9, and 11.0mL iron standard solution in a group of 100mL bottle, according to the sample solution method to measure its absorbance standard curve from the standard curve to detect iron oxide content. The percent content of ferric oxide by the following formula: Type C - check the ferric oxide content of the sample from the standard curve, mg/100mL; G - sample weight, G. Two. Det