毛细管气相色谱法同时测定空气和废气中多种常见有机污染物.PDFVIP

毛细管气相色谱法同时测定空气和废气中 多种常见有机污染物 杨丽莉 纪英 胡恩宇 母应锋 （南京市环境监测中心站 南京 2 100 13） E-mail:yllyj @126.com 摘 要 采用活性炭吸附空气和废气中常见的有机物苯、甲苯、乙苯、对- 二甲苯、间- 二甲苯、邻- 二甲苯、丙酮、 正丁醇、苯乙烯和环己酮，二硫化碳解析后用毛细管气相色谱法同时测定，各组分线性响应良好，曲线相关系数≥0.999；灵 敏度高，检出限在0.0 1～0.05 μg 之间；回收率80 ％，与相关国标和企业标准相比，操作简单、实用、快速、准确。完全适 合环境空气和工业废气中多种有机物的监测。 关键词 毛细管气相色谱法；多种有机物；空气和废气 中图分类号 O657.7 Determination of Multi Organic Compounds in Air by Capillary Gas Chromatography Yang Lili , Ji Ying, Hu Enyu, Mu Yingfeng (Nanj ing environment monitoring center, Nanj ing 2 100 13, China) d Abstract A quick and effective determination method of ten organic compounds ( benzene, toluene, ethyl benzene, xylene, acetone, butanol, styrene and cyclohexanone) in air has been established. The sample was collected with activated carbon and e dissolved with 1.0 mL CS , 1.0 μL of the solution was inj ected on a DB-FFAP capillary column (30m ×0.32 i.d. ×0.25 μm ) 2 r and determined by GC-FID. The ten kinds of organic compounds were separated each other completely. The detected limits in sample were 0.01~0.05 μg. The average recoveries were 80%. The relative standard deviations was 0.36%. This method is e simple, rapid and sensitive. t Key words Multi organic compounds; gas chromatography; air s i 1 引 言 采样简单方便，分析测定快速，准确度好，灵敏度高，适 合对环境空气和工业废气中多种挥发性有机物进行监测。 g 苯、甲苯、乙苯、二甲苯、丙酮、正丁醇、苯乙烯