低聚羧甲基瓜胶可再生凝胶体系的流变特性-高校化学工程学报.pdf

第25 卷第4 期 高 校 化 学 工 程 学 报 No.4 Vol.25 2011 年 8 月 Journal of Chemical Engineering of Chinese Universities Aug. 2011 文章编号：1003-9015(2011)04-0584-06 低聚羧甲基瓜胶可再生凝胶体系的流变特性 唐美芳, 苏 创, 方 波 (华东理工大学 化学工程研究所 化工流变学研究室, 上海 200237) 摘 要：低聚瓜胶压裂液在低渗透油气田开发增产中有重要的应用。今对硼砂交联低聚羧甲基瓜胶可再生凝胶体系进 行了研究。考察了低聚羧甲基瓜胶浓度、硼砂浓度对凝胶形成以及再生的影响，获得了结构稳定的可再生凝胶体系。 考察了不同再生次数的凝胶体系的流变特性，结果表明可再生凝胶体系具有良好的黏弹性、触变性和剪切变稀性。低 聚羧甲基瓜胶可再生凝胶体系的流变曲线可用非线性共转Jeffreys模型描述，模拟值与实验值吻合良好。 关键词：低聚羧甲基瓜胶；交联；再生；黏弹性；触变性；剪切变稀性 中图分类号： O648.17 ；TQ427 ；O377 文献标识码：A Rheological Properties of the Regenerable Gel Systems of Low Molecular Weight Carboxymethyl Guar Gum TANG Mei-fang, SU Chuang, FANG Bo (Research Laboratory of Chemical Engineering Rheology, Chemical Engineering Research Center, East China University of Science and Technology, Shanghai 200237, China) Abstract: Low molecular weight guar gum fracturing fluids play an important role in the enhancement of oil-gas recovery for low permeable oil-gas reservoirs. The production of the regenerable cross-linked gel systems consisting of low molecular weight carboxymethyl guar gum (LMWCMG) and borax were studied. The effects of LMWCMG concentration and borate concentration on the formation and regeneration of the gel systems were investigated, and the stable can be regenerated LMWCMG cross-linked gel systems were obtained. Furthermore, the rheological properties of the gel systems with different regeneration times were studied. The results show that the regenerable gel systems possess good visco-elasticity and thixotropy, and shear thinning