热活化污泥—粉煤灰复合地聚合物的性能与机理研究-同济大学学报.DOCVIP

热活化污泥—粉煤灰复合地聚合物的性能与机理研究 郭晓潞1, 2,施惠生1, 2 (1先进土木工程材料教育部重点实验室（同济大学），上海201804; 2同济大学环境材料研究所，上海201804）摘 要：与传统水泥相比，地聚合物是一种低碳排放且能源、资源消耗较少的新型胶凝材料。本文研究了利用高钙粉煤灰和热活化污泥研制复合地聚合物的可行性，并研究了复合地聚合物的性能与。研究表明：经900℃焙烧1 h的污泥（45 (m）以10%的掺量取代粉煤灰后研制成的地聚合物具有较好的抗压强度；在复合地聚合物体系中，无定形地聚合物凝胶包裹在球状粉煤灰颗粒周围，有类沸石矿物生成，出现了Al-O/Si-O对称伸缩峰及Si-O-Si/Si-O-Al弯曲振动峰。这一研究可以丰富地聚合物原材料的选择，有助于多种工业废弃物，尤其是含硅铝相含钙工业废弃物的资源化利用。 关键词：热活化污泥，粉煤灰，地聚合物，抗压强度，机理中图分类号: TQ172 文献标志码: A 文章编号: PERFORMANCES AND MECHANISM OF COMPLEX GEOPOLYMERS PREPARED FROM THERMALLY-TREATED SLUDGE AND HIGH-CALCIUM FLY ASH GUO Xiaolu1, 2, SHI Huisheng1, 2 (1Key Laboratory of Advanced Civil Engineering Materials (Tongji University), Ministry of Education, Shanghai 201804; 2 Institute of Environmental Materials, Tongji Universiy, Shanghai 201804) Abstract: Compared to the ordinary Portland cement, geopolymer is a new type of cementitious material which is a low carbon, energy and natural sources saving material. In this paper, the feasibility of a complex geopolymer prepared from high-calcium fly ash and thermally-treated sludge was studied, and the performance and mechanism of the geopolymer were also studied. The results showed that compressive strength of the geopolymer was better when 10% fly ash was replaced by thermally-activated sludge (45 (m) at 900℃ for 1 hour. In complex geopolymeric matrix, amorphous geopolymeric gel covered around spherical fly ahs granule, the Zeolite-like mineral formed, meanwhile, the asymmetric stretching Al-O/Si-O bonds and Si-O-Si/Si-O-Al bending band appeared. This work is beneficial for extending raw materials of geopolymer, and also for utilizing of multi industrial wastes, especial the wastes containing silicate-aluminum phase and calcium. Key words: Thermally-treated sludge, fly ash, geopolymer, compressive strength, mechanism research 收稿日期：2011-06-XX 基金项目：国家自然科学基金（项目批准号、高等学校博士学科点专项科研基金20090072110010）同济大学青年优秀人才培养行动计划2009KJ005）资助。（19），，主要E-mail： 与传统水泥相比，地聚合物是一种低碳排放且能源和资源消耗较少的新型