NaCo2O4晶体的生长,形貌和生长机理研究.pdfVIP

Growth, Morphology and Growth Mechanism of NaCo2 O4 Crystals HAN Shu-juan1WANG Ji-yang1 LI Jing1 GUO Yong-jie1 WANG Yong-zheng1 ZHAO Lan-ling1 YAO Shu-hua2, CHEN Yan-bin2, Boughton R. I 3 1. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China; 2. College of Materials Science and Engineering, Nanjing University, Nanjing 210093, China; 3. Department of Physics and Astronomy, Bowling Green State University, Bowling Green, Ohio 43403, USA Abstract:Millimetre-sized NaCo2O4 crystals were grown from a molten flux based on NaCl-Na2CO3 by spontaneous nucleation method. Details of the preparation and growth procedures are provided. The as grown crystals were characterized by X-ray powder diffraction (XRPD). The morphology and growth mechanism were investigated by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The results show that the obtained crystal are well crystallized and indexed in a hexagonal crystal system with lattice parameters a = b = 0. 2842 nm, c = 1.0894 nm, and V = 0. 0761997 nm3. The growth of NaCo2O4 single crystals was controlled by a two-dimensional (2D) layer-by-layer mechanism acting along the c-axis. Furthermore, the morphology of the crystals was also interpreted in the viewpoint of anionic coordination polyhedron growth units. layered compounds; crystal growth; microstructure O78 A 1000-985 X (2012) 03-0573 -05 NaCO2O4晶体的生长，形貌和生长机理研究 韩树娟1王继扬1 李静1郭永解1王永政1赵兰玲1 姚淑华2陈延彬2Boughton R. I. 3 1.山东大学晶体材料国家重点实验室，济南250100;2.南京大学材料科学与工程学院，南京210093； 3.博林格林州立大学天文和物理学系，俄亥俄博林格林43403 摘要：采用自发成核方法，以NaCl-Na2CO3为助熔剂，生长了毫米级的NaCo2O4晶体。通过X射线衍射对晶体作了 表征。利用扫描电子显微镜和原子力显微镜研究了晶体的形貌和生长机理。结果表明：所得晶体是NaCo2O4，属于 六方晶系，晶胞参数