食品包装用PVC 瓶盖垫片中增塑剂DEHP 的迁移研究[J].pdf

PACKAGING ENGINEERING Vol. 32 No.01 2011. 1 60 食品包装用PVC 瓶盖垫片中增塑剂DEHP 的迁移研究 贾 芳, 李慧勇, 王继才, 席绍峰, 谭建华, 赵田甜 (, 510110) : 为了解PVC 垫片接触各类食品的安全 , 采用气相色谱质谱联用法研究了PVC 垫片中DEHP 在乙醇 和正己烷中的迁移行为及其影响因素实验结果表明: 随着时间的延长, DEHP 的迁出量逐渐增加;PVC 垫片 厚度越小, DEHP 越容易迁出; 与乙醇相比,DEHP 更容易向正己烷中迁移,PVC 垫片应避免接触脂肪类食品 : PVC 垫片; DEHP; 迁移; 气质联用法; 红外光谱法 : TS206; T 487 : A : 1001- 3563( 2011)01- 0060- 03 Study on Migration of DEHP in PVC Gasket of Food Packaging J I A Fang , L I H uiy ong , WA N G J ic ai , X I Shaof eng , T A N J i anhua, ZH A O T i ant ian (Guangzhou Institute of Quality Supervision and Testing, Guangzhou 510110, China) Abstract: The migration of DEHP in PVC gasket dipped in ethanol and nhexane and its influencing factors w ere studied to find out the security of polyvinyl chloride (PVC) gasket. T he tests show ed that the migration quanti ty increased with the dipped time increase; the migration was easier w hen the PVC gasket w as thinner; the mi gration of DEHP from PVC gasket to nhexane w as easier than to ethanol. It w as suggested that PVC gasket should avoid contacting fatty food. Key words: PVC gasket; DEHP; migration; GCMS; IR spectrometry (2) (DEHP) , ( PVC) , DEHP , 1 , , ; DEH P 1. 1 [ 1- 2] DEHP PVC PVC : 1 ( 0. 5 mm) 2 ( , DEHP PVC 1.0 mm) ; ( 2) : , 99%; :; :; : , DEH P PV C ; , : Agilent [ 3- 4] G 14944- 1994 , : Vertex70 [ 5] , 1. 2 , : HP5 ( 30 m 250 m 0. 25 m) , : 280 , : 20 ! 1,