锌掺杂对SrTi03 光催化性能的影响.pdf

第38卷第4期 燃料化学学报 Vol_38NO．4 2010年8月 JournalofFuel and ChemistryTechnology Aug．2010 文章编号：0253-2409(2010)04-0502-06 锌掺杂对SrTi03光催化性能的影响 王桂赘，秦娅，成洁，王延吉 (河北丁业大学化工学院，天津300130) 摘要：制备了锌掺杂的SrTiO，光催化剂，测试了掺杂样品在400W高压汞灯照射下，分解纯水制氢的活性。考察了锌的掺 oC 明，zn掺人可显著提高SrTiO，的光催化活性，适宜的锌掺杂摩尔分数为I％左右，相应的掺杂量下，适宜的焙烧温度为950 左右，上述条件制得掺锌SrTiO，的产氢速率较未掺杂样品提高了120％左右。表征结果冠示，掺摩尔分数I％的锌未改变 SrTiO，的晶体结构及结晶完整性，但样品表而发生了锌的富集，而且在一定的掺杂范围内，锌掺杂使SrTiO，催化剂的粒度有 关键词：锌；钛酸锶；光催化；分解水 中图分类号：0643文献标识码：A InfluenceofZn onthe of doping photocatalyticpropertySrTi03 WANG Gui—yun，QINYa，CHENGJie，WANGYan-ji (SchoolofChemical 300130，China) Engtneering，HebeiUniversityofTechnology，Tianjin Abstract：TheZn were andthe ofthe SrTi03 activitydoped doped photocatalystssynthesizedphotocatalytic samples forwater to wasmeasuredundertheirradiationofa W1．The decompositionhydrogen highpressureHglamp(400 influenceof amountofZnandthecalcination onthe were doping temperaturephotocatalyticactivityinvestigated． The of withand Zn werecharacterized andUV— without physical catalysts doping usingXRD，XPS，SEM properties visiblediffusereflectance resultsshowthatZn the spectra．Theexperimental dopinggreatlyimproves is inthis suitablecalcina