煤矸石动态煅烧活化的影响因素-环境工程学报.pdfVIP

第 11卷　 第7 期 环 境 工 程 学 报 Vol. 11,No.7 2 0 1 7 年 7 月 Chinese Journal of Environmental Engineering July 2 0 1 7 煤矸石动态煅烧活化的影响因素 1 1,∗ 1 1 2 李超 ,赵亮 ,惠晓梅 ,袁进 ,高成伟 1. 山西省生态环境研究中心,太原 030009 2. 山西双良国环科技有限公司,太原 030033 摘　 要　 煤矸石能够通过热活化激发胶凝活性,用做水泥混合材,实现综合利用。 本研究以太原西铭煤矿洗选矸石为研究 对象,采用单因素实验法考察了煅烧方式、温度、时间和粒度对活化效果的影响,利用 TG-DTA、XRD 以及 IR 等分析手段探 讨了不同因素对煤矸石煅烧活化的影响机制。 研究结果表明,煤矸石活性主要受高岭石晶相转变和残余碳的影响。 与静 态煅烧相比,动态煅烧传热和氧传递效率更高,煤矸石活化效果较好。 温度升高,物料活性提高,但是超过 800 ℃后,活化 效果变差。 随着活化时间增加,煤矸石活性提高,超过60 min 后,活性保持稳定。 粒度减小,可以提高传热和氧传递效率, 改善活化效果,当粒度达到 10 ~100 μm后,继续减小粒度并不能提高活化效果,因此,煤矸石动态煅烧活化粒度以保持在 10 ~100 μm 为宜。 关键词　 煤矸石;动态煅烧;水泥混合材;固体废物 中图分类号　 X705　　 文献标识码　 A　　 文章编号　 1673-9108(2017)07-4349-06　　 DOI　 10.12030/ j.cjee.201701122 Influence factors of dynamic calcinations for coal gangue activation 1 1,∗ 1 1 2 LI Chao ,ZHAO Liang ,HUI Xiaomei ,YUAN Jin ,GAO Chengwei 1.Research Centre for Eco-Environmental Sciences in Shanxi,Taiyuan 030009,China 2.Shanxi Shuangliang Guohuan Technology Co. Ltd. ,Taiyuan 030003,China Abstract　 The coal gangue can be activated by thermal treatment,and then used as cement mixture. In this paper,the effect of treatment methods,temperature,time and particle size on the activation was investigated by single factor experiments,while washing coal gangue from Ximing Mining of Taiyuan used as subjects. The influ- ence mechanism was also studied by TG-DTA, XRD and IR. The results indicated that the activity of coal gangue was mainly affected by the kaolinite transformation and the residual carbon. Compared with the static cal- cination,higher heat and oxygen transfer efficiency were achieved by dynamic calcination. Therefore the higher activity was obtained. The activity also can be improved with increasing temperature,until the temperature ex- c