废镍氢电池中镍、钴和稀土金属回收工艺研究.doc

废镍氢电池中镍、钴和稀土金属回收工艺研究 34??j??71?( Vol134j?No11 ??j??Hj???j??? CHINESEJOURNALOFRAREMETALS 2010??1?C Jan12010 j??r?w???(:2009-04-10;???????(:2009-05-15 j??????????????3???????/???L???????1???,?v???????C?h?8???[???2(6) j????o?????cj???(),??,??????????,?????M???(;?M?????A???1???[???2 3(f@63) ?????,?v???d??j3???????(???????r?????M?? ?cj???,?6?m?? 3 (?????????2???.???????O?(?????E????,????????113001) ????:???????????V?l???????????,?v???d??j3??j3???((RE)?????????r,?1????????????j3??????j3?????;?????????????h???P???6?? ??j3??j3???(????????????;????pHj3???c???????O???????dRE3+ ?????M??j3?????h???P???6?????(???r????????j4?:???????????????? ??j3??j3???(?8???????d???a?2???????????????(???(?J?????????a?2????????j4???????????O,?a?2?????????????B:?????????B3.8h, ???????B15,?????;???????B1.8mol??L-1 ,?????h??80)1j4?8?a?2?????????E,????????????96.8%,????????????97.3%,???(?????? ????94.6%j4???(?J?????a?2?????????B:????pH?B2.0,???c???????O???????dRE 3+ ?????M???B4,?????h???B60)1j4?8???????E,RE ???r???B96.7%j4 ???i??:???,?v??;??;??;???( doi:10.3969/j.issn.0258-7076.2010.01.016 ?d???l????:TG139j?j????i?N???3:Aj?j??????2??:0258-7076(2010)01-0079-06 RecoveryofNi,Co,RareEarthfromWasteMH2NiBattery WuWei,ZhangHonglin 3 (CollegeofEnvironmentandBioengineering,LiaoningShihuaUniversity,Fushun113001,China) Abstract:TherecoveryofNi,Co,REfromMH2Nibatterywithwettreatmentwasintroduced,theimpactofleachingtime,liquid2 solidratio,sulfuricacidinitialconcentrationandleachingtemperatureontheleachingrateofNi,Co,REandtheimpactofsolution pH,themolarratioofNa2SO4andleachingsolutionwithRE 3+ ,reactiontemperatureandotherfactorsontherecoveryrateofREwere studied.Bytheorthogonaltest,theoptimizedsulfuricacidleachingconditionsforNi,Co,REandtheoptimizedprecipitationcondi2 tionsforrareearthdoublesaltwereidentified.Theresultsshowedthattheoptimizedsulfuricacidleachingconditionswereleaching timeof3.8h,liquid2solidratioof15,initialconcentrationofsulfuricacidof1.8mol??L -1 ,andleachingtemperatureof80)1.The leachingrateofNi,C