硫酸钙在盐水中的溶解度及溶度积实验研究.docx

创新技术硫酸钙在盐水中的溶解度及溶度积实验研究颜亚盟，张仂(中盐工程技术研究院有限公司 天津 300450)摘 要：测定了硫酸钙在不同温度和不同浓度盐水溶液中的溶解度，并分析了盐水溶液中各离子对钙离子的溶解浓度的影响及盐水浓度、温度对硫酸钙溶解度及溶度积的影响。结果表明：钙离子的溶解浓度随溶液中氯离子、镁离 子、钾离子浓度的增加先增加后降低，随硫酸根浓度的增加先减小后增加；硫酸钙的溶解度随氯化钠浓度的增加先 增加，中间出现一个极大值后再降低；在盐水浓度为 25%时，硫酸钙的溶解度随温度升高，在 70 ℃时达到最高， 而后降低；硫酸钙的溶度积随盐水浓度的增加先升高再降低。关键词：硫酸钙 盐水 溶解度 溶度积中图分类号：TQ95文献标志码：A文章编号：1006-8945(2014)10-0013-05DOI:10.14099/j.cnki.tjkj.2014.10.003Solubility and Solubility Product of Calcium Sulfate in BrineYAN Yameng，ZHANG Le(Engineering Technology Institute Co.，LTD. of CNSIC，Tianjin 300450，China)Abstract：The solubility of calcium sulfate in brines with different concentrations and temperatures was studied. Theeffects of different ions in brine on concentration of calcium ion and the effects of brine concentration and tempera- tures on the solubility and solubility product of calcium sulfate were analyzed. Experimental results indicated that the solubility of calcium ion first increased and then decreased along with the increasing of the concentration of chloride ion，magnesium ion，and potassium ion；first decreased and then increased along with the increasing of the concen- tration of sulfate ion. The solubility of calcium sulfate first increased，after reaching a maximum value and then de- creased along with the increasing of the concentration of sodium chloride. In the 25% brine，the solubility of calcium sulfate first increased slowly and then decreased along with the increasing of temperature. Under 70 ℃，the solubility of calcium sulfate reached the highest level and then decreased. The solubility product of calcium sulfate increased first and then decreased with the increasing of the concentration of brine.Key words：calcium sulfate；brine；solubility；solubility product了大量研究。[2-6]本文着重以制盐行业生产的精制盐为原料，研究硫酸钙在盐水中的溶解度，对预防蒸发 制盐过程中和设备中硫酸钙结垢具有重要参考价值。0引言-制盐行业生产的原料卤水中除含有较高浓度的NaCl 外，还含有少量的 Ca2+、SO42 等杂质离子[1]，其 中钙离子在蒸发浓缩制盐过程中会形成 CaSO4 等难 溶物，在卤水输送、预热、蒸发过程中形成的硫酸钙 在输送管路和蒸发罐加热管壁上结垢，影响蒸发传热效果。由于设备结垢，使得在生产过程中需要周期性 的用水或酸清洗加热管道和蒸发装置，消耗过多的蒸 汽等能