专题之动力学光谱激光化学和光化学动力学类-物理与电子信息.PDF

墙贴摘要正文 专题之三、动力学光谱、激光化学和光化学动力学类 P3-70 An efficient quantum approach for studying the interaction of atoms and circularly polarized laser fields Minghu Yuan, Tianshu Chu, Keli Han* State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics， Chinese Academy of Sciences, Dalian, 116023, China We present anefficient quantum approach for exploring physical processes of various atomic targets interacting with strong circularly polarized laser fields, based on thesine-DVR method[1, 2] which is high-efficiency and accurate for studying the interaction of atoms/molecules and linearly polarized laser fields.However, the sine-DVR method is helpless when atoms/molecules exposed in circularly polarized laser fields. In this work, we introduceWigner rotation in the time propagation due to the circularly polarized light can be deemed to the rotation of linearly polarized light with time. We determine the interactions of electron with nuclei and field in laboratory fixed coordinate system, respectively.Every step can be split into three sub-steps.Firstly, we assume that the atoms/molecules main axis is parallel with the zaxis and the polarization direction of laser is arbitrary. Then we can calculate the interaction of electron with nuclei. Secondly, we transform the electron wave function with the Wigner rotation matrix making that the polarization direction of laser is parallel with the z axis. So, we can calculate the interaction of electron with field. Thirdly, we can return to the electron wave function by the inverse rotation, and calculate the interaction of electron and nuclei.The processes are showi