浙江大押艇物理化学甲.pptVIP

Chapter 3 The First Law: the machinery 3.1 State functions and path functions 3.2 Changes in internal energy 3.3 The relation between Cv and Cp 2.The Joule experiment, U and H of perfect gas 3.4 Throttling expansion (节流膨胀) and the Joule-Thomson effect * * 热力学第一定律 First law of thermodynamics State functions Path functions Exact differentials Inexact differentials 状态函数法 Definition: Internal pressure 1. The relation between Cv and Cp （1）定性分析： ，吸收的热量转化为 ，还要反抗外压做体积功 恒压加热， 恒容加热，不做功，吸收的热量转化为系统的 热力学能（内能） 所以，每升高一度，恒压过程所需热比恒容过程大: CpCv (2) 定量计算： 恒压下两边除以dT，得: Definition: Internal pressure Expa