氢气泡模板电沉积法制备三维多孔超疏水氧化铅膜-中国电镀网.pdfVIP

中国科技论文在线 氢气泡模板电沉积法制备三维多孔超疏水 氧化铅膜# 李超，李则林** 5 （湖南师范大学化学化工学院，长沙 410081 ） 摘要：应用阴极析氢气泡模板电沉积法分别在紫铜片和黄铜网上沉积了三维多孔铅膜，再灼 烧氧化成多孔氧化铅膜，用扫描电子显微镜和 X-射线衍射分析了氧化铅膜的表面形貌及物 相组成。该氧化膜表面显示出超疏水性，水滴在其表面的接触角最高达到 155°。沉积了多 孔氧化铅的铜网同时具有超疏水性和超亲油性。其与水的接触角为 152°，与煤油的接触角 10 小于5°，可用于煤油与水的混合物的分离。 关键词：氢气泡模板；三维多孔；接触角；超疏水。 中图分类号：O64 Electrodeposition of three-dimensional porous 15 superhydrophobic lead oxide films using hydrogen bubbles as a template LI Chao, LI Zelin (College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China) 20 Abstract: Using cathodic hydrogen bubbles as templates, three dimensional (3D) porous lead films were respectively electrodeposited on the substrates of copper wafers and copper grids, which were then oxidized to porous lead oxides by heating the deposits in the air. Scanning electronic microscope (SEM) and X-ray diffraction （XRD ）were employed to characterize the surface topography and phase composition of the as-prepared porous films. The porous films showed superhydrophobicity and the 25 maximum contact angle reached to 155°. The copper grids covered with the porous lead oxide deposit showed both superhydrophobicity and superoileophilicity and the contact angles were 152° and less than 5° for water and kerosene, respectively. The copper networks can be used in separating the mixture of kerosene and water. Key words: hydrogen bubble dynamic template; three-dimensional pores;