超细银粉的制备及其导电性研究.docVIP

 超细银粉的制备及其导电性研究 孟淑媛 1，吴海斌 1，吴松平 1,2，唐元勋 1 （1. 广东风华高新科技集团有限公司，广东 肇庆 526020；2. 华南理工大学，广东 广州 510640） 摘要:用化学还原法在醇水体系中制备出平均颗粒粒径为 0.8~1.2 μm、分散性好的超细球银。讨论了表面活性剂、 还原剂的种类、温度、硝酸银含量及 pH 值对球银颗粒粒径和分散性的影响。将所得超细球银在水体系中高效率球磨 得分散性好的光亮片状银粉，平均粒径＜6 ìm，比表面积 0.7~1.3 m2/g。讨论了吸附在银粉表面的有机物的种类和比表 面积对片银导电性能的影响,结果表明：比表面积越大，导电性越好。 关键词: 超细银粉；片状银粉；导电性能；球磨 中图分类号: TM241 文献标识码:A 文章编号:1001-2028（2004）07-0035-03 Preparation of Ultrafine Silver Powder and Its Electrical Properties MENG Shu-yuan1, WU Hai-bin1, WU Song-ping1,2, TANG Yuan-xun1 (1. Guangdong Fenghua Advanced Technology Group Co. Ltd, Zhaoqing 526020, China; 2. South China University of Technology, Guangzhou 510640, China) Abstract: In alcohol-water system, AgNO3 is reduced to ultrafine spherical silver powders with average particle size 0.8~1.2 ìm and excellent dispersity by chemical reduction method. The effect of reductant, the content of silver nitrate, reaction temperature and pH value on particle size and dispersity of spherical silver powder were analyzed. The ultrafine flake silver powder in excellent dispersity was prepared by milling above-mentioned ultrafine spherical silver powder in aqueous medium. Particle size of the flake silver powder is less than 6 ìm, and its specific surface area in the range from 0.9 to 1.3m2/g. The influences of the kind of surfactant and specific surface area on electrical properties of flake silver powder were investigated, and the results show that conductibility of flake silver powder increases with the increasing specific surface area. Key words: ultrafine silver powder; flake silver powder; electroconductive properties; mill 超细银粉在贵金属导电浆料中有广泛的应用。随着 低温固化浆料的应用和发展，片状银粉的应用越来越广 泛。片银作为填料导电时其相互间是面或线接触，从而 形成网络结构，电阻远较球状者的点接触低得多[1]，甚 至在较低银含量和较薄印刷涂层时仍具有较高的电导 率，因此广泛应用于碳膜电位器端头、薄膜开关、滤 波器等电子元器件中。片状银粉的物理性能是影响银 浆电性能的重要因素[2] ，而欲得到电导率好的片状银 粉，制备出合适的前驱体球银也是至关重要的。 文献中较少提及片银前驱体球银的制备和特性要 求，偶有采用将普通银粉进行粉碎再球磨的方法制备 片银的报道，惜其既耗能又影响片银质量。本公司采 用化学还原法在醇水相中用抗坏血酸还原 AgNO3 得 超细球银，球银经高效球磨得光亮片银，片银应用于 低温固