KI与无机铵盐催化CO2与环氧丙烷合成碳酸丙烯-上海有机化学研究所.PDFVIP

2010 年第68 卷 化 学 学 报 Vol. 68, 2010 第9 期, 870～874 ACTA CHIMICA SINICA No. 9, 870～874 ·研究论文· KI 与无机铵盐催化 CO2 与环氧丙烷合成碳酸丙烯酯 周 喜a,b 杨先贵a 姚 洁a 王公应*,a (a 中国科学院成都有机化学研究所 成都 610041) (b 中国科学院研究生院 北京 100049) 摘要 以无毒、合成简单、廉价的无机铵盐(氨基甲酸铵、碳酸氢铵、碳酸铵等)为助催化剂, 研究其对卤化钾(KCl、 KBr 、KI)催化 CO2 与环氧丙烷合成碳酸丙烯酯(PC)的影响. 结果表明, 卤化钾与无机铵盐显示出很好的协同催化效应. 其中以氨基甲酸铵为助催化剂, KI 为主催化剂时, 催化合成PC 的效果最好. 同时考察了催化剂用量、反应温度、CO2 初始压力、PC 的预加入量、反应时间等因素对反应的影响. 在优化条件下, PC 收率大于99%. 关键词 二氧化碳; 环氧丙烷; 碳酸丙烯酯; KI; 无机铵盐 Synthesis of Propylene Carbonate from CO and Propylene Oxide 2 with KI and Inorganic Ammonium Salts as Catalyst Zhou, Xia,b Yang, Xianguia Yao, Jiea Wang, Gongying*,a a ( Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041) (b Graduate University of Chinese Academy of Sciences, Beijing 100049) Abstract Synthesis of propylene carbonate (PC) from CO and propylene oxide catalyzed by potassium 2 halide (KCl, KBr, KI) in the presence of inorganic ammonium salt (ammonium carbamate, ammonium bi- carbonate, ammonium carbonate) was studied. It was discovered that potassium halide and inorganic ammo- nium salt showed excellent synergetic catalytic effect, and ammonium carbamate showed the best co-catalytic effect among of them when KI was used as main catalyst for PC synthesis. Effects of amount of catalyst, reaction