环戊二烯衍生物的合成及应用研究进展-上海有机化学研究所.PDFVIP

DOI: 10.6023/cjoc201512012 综述与进展 有机化学 Chinese Journal of Organic Chemistry REVIEW 环戊二烯衍生物的合成及应用研究进展 叶俊伟 黄雪明 王潇潇 郑 婷 高 远 贡卫涛 宁桂玲* (大连理工大学化工与环境生命学部化工学院 精细化工国家重点实验室 大连 116024) 摘要 环戊二烯及其衍生物是一类重要的小分子环烯烃化合物, 在金属茂化合物合成、有机中间体合成和有机光电材 料等领域具有重要应用价值. 结合本课题组的研究成果, 主要综述环戊二烯衍生物的合成研究进展, 并介绍一些典型 的环戊二烯衍生物在有机合成领域应用研究进展. 关键词 环戊二烯衍生物; 合成; 应用; 金属茂化合物; 有机中间体 Research Progress on the Synthesis and Application of Cyclopentadiene Derivatives Ye, Junwei Huang, Xueming Wang, Xiaoxiao Zheng, Ting Gao, Yuan Gong, Weitao Ning, Guiling* (State Key Laboratory of Fine Chemicals and School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024) Abstract Cyclopentadiene and its derivatives are a type of important small molecule cyclic olefin compounds, which have been widely applied in many fields such as synthesis of metallocene compounds, synthesis of organic intermediates and or- ganic photoelectric materials. Based on our recent research results, in this review, the research progress on the synthesis of cyclopentadiene derivatives and the application of some typical cyclopentadiene derivatives in the field of organic synthesis are summarized. Keywords cyclopentadiene derivatives; synthesis; application; metallocene compounds; organic intermediates 环戊二烯及其衍生物由于具有独特的五元环与共 二烯粗产品为原料制备较高纯度环戊二烯. 首先将粗产