溶剂热方式制备高荧光量子点.pptxVIP

Solvothermal conversion of coal into nitrogen-doped carbon dots with singlet oxygen generation and high quantum yieldTeacher: Lan Yu-weiReporter: Tan Yan-fang1 IntroductionCarbon dots (CDs), a kind of newly emerged fluorescent nanomaterial, have been synthesized from various kinds of carbon sources including fullerene, graphite, graphene oxide, carbonnanotubes and carbohydrates by top-down methods. Among these carbon sources available now, low-cost and earth-abundant coal has demonstrated a unique and charming superiority .However, all of the approaches mentioned above are carried out in the presence of concentrated acid, which are time-consuming, environmentally unfriendly along with a relatively low QY.2 Materials One kind of Chinese anthracite from Taixi coal mineDMF(dimethyl formamide)AIBN(Azobisisobutyronitrile)MMA(methyl methacrylate) ExperimentsSupernatant centrifuging at9000 rpm for 30 minPristine anthraciteultrasonication for 1 hN-CDsCrushedand dispersed in rotary evaporationa Teflon-lined stainless steel autoclave 180℃ 12h20ml 2.5mg/mL DMFDMFcarbogenic dotschemical oxidationanthraciteSingle coal-based CDs300mg AIBNadding the N-CDsultrasonically dispersed intoN-CDs-PMMAsolidifying at 50 C for24 h5mL MMAQY measurementQY determination was achieved according to the previously established procedure . Rhodamine B (literature QY 0.31 at 340 nm) was selected as a reference. The QYs were calculated by comparing the integrated PL intensity (excited at 340 nm) and the absorbance value (at 340 nm) of the standard with each of the coal-based CDs, based on the following equation:1O2 generation QY ( ) measurement1O2 generation QY () was calculated according to the following equation.where ‘‘unk” and ‘‘std” designate the ‘‘N-CDs photosensitizer” and‘‘Ir(ppy)2bpy”, respectively, ‘‘m” is the slope that is calculated by the curve of DPBF absorbance (414 nm) versus irradiation time, and ‘‘F” is the absorption correction factor, which is given by F = 1–10A3 Results and di