亚热带竹林地区的臭氧及其影响因子.pdfVIP

Advances in Geosciences 地球科学前沿, 2017, 7(4), 536-551 Published Online August 2017 in Hans. /journal/ag /10.12677/ag.2017.74055 Ozone and Its Affecting Factors in the Subtropical Bamboo Forest Jianhui Bai Laboratory for Middle Atmosphere Layer and Globe Environment Observation, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing nd th th Received: Jul. 22 , 2017; accepted: Aug. 8 , 2017; published: Aug. 15 , 2017 Abstract During July 2012-January 2013, integrated measurements of biogenic volatile organic compounds (BVOCs), O3 and solar radiation at a subtropical bamboo forest, Zhejiang province, were carried out. Based on PAR energy balance and empirical models of isoprene and monoterpene emissions at canopy scale, O3 empirical models considering the relationships between O3 and isoprene and O3 and monoterpenes, respectively, were developed. O3 diurnal variation and mean value were better simulated by O3 empirical models. The validation of O3 empirical models was made, which showed that it can capture O3 variation characteristics. A sensitivity study of the response of O3 to changes in its controlling factors (i.e., isoprene or monoterpenes, PAR, water vapor and S/Q-scat- tering factor, ratio of solar scattering radiation to solar global radiation) showed that O3 was most sensitive to PAR, and more sensitive to water vapor, isoprene emission and S/Q, for O3 empirical model considering the relationship of O3 with isoprene emission; O3 was also most sensitive to PAR, and more sensitive to water vapor, S/Q and monoterpene emissions, for O3 empirical model considering the relationship of O3 with monoterpene emissions. The responses of O3 to