一种高效、灵敏测定汞离子磷光量子点传感器.pdfVIP

Advances in Material Chemistry 材料化学前沿, 2016, 4(4), 57-63 Published Online October 2016 in Hans. /journal/amc /10.12677/amc.2016.44007 An Efficient and Sensitive Sensor of Phosphorescence Quantum Dots for Determining Hg2+ Ji Chang, Hairong Zhang* Institute of Biochemical Analysis Technology, Xinzhou Teachers University, Xinzhou Shanxi th th th Received: Sep. 26 , 2016; accepted: Oct. 12 , 2016; published: Oct. 18 , 2016 Copyright © 2016 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Open Access Abstract The novel Mn-doped ZnS quantum dots of phosphorescence were synthesized in aqueous solution with D-phenylalanine as a stabilizer, which was characterized by fluorescence spectrometry and SEM, respectively. Effects of various factors including the concentration, temperature and pH of quantum dots on sensor were discussed. The results showed that the concentration of Hg2+ in the range of 1.0 × 10−5 mol/L to 8.0 × 10−7 mol/L had good linear relationship, a new method of the determination Hg2+ the sensor had good recognition ability for Hg2+, the detection limit was 2.6 × 10−8 mol/L, and the relative standard deviation was 3.30%. The method can be used to determine Hg2+ in pond water. Keywords Mn Doping ZnS Quantum Dots, Room Temperature Phosphorescence, Hg2+, Quenching 一种高效、灵敏测定汞离子磷光量子点传感器 常 吉，张海容* 忻州师范学院生化分析技术研究所，山西 忻州 *通讯作者。 文章引用: 常吉, 张海容. 一种高效、灵敏测定汞离子磷光量子点传感器[J]. 材料化学前沿, 2016, 4(4): 57-63. /10.12677/amc.2016.44007 常吉，张海容 收稿日期：2016年9月26 日；录用日期：2016年10月12 日；发布日期：2016年10月18 日 摘 要 以D-苯丙氨酸为稳定剂，合成具有室温磷