酚醛比对特辛基苯酚甲醛树脂结构的影响.pdfVIP

Hans Journal of Chemical Engineering and Technology 化学工程与技术, 2017, 7(4), 147-153 Published Online July 2017 in Hans. /journal/hjcet /10.12677/hjcet.2017.74022 Influence of Molar Ratio of P-Tert-Octyl Phenol and Formaldehyde on Structure of the Resin 1 2* 2 2 1 Xuemei Liu , Junli Tan , Mingtao Lin , Yuping Chen , Yu Fang 1 Nanjing General Company for Science Technology Development Research Institute of Chemical Industry of Forest Products, CAF, Nanjing Jiangsu 2 Institute of Chemical Industry of Forest Products, CAF, Nanjing Jiangsu st th th Received: Jun. 21 , 2017; accepted: Jul. 8 , 2017; published: Jul. 11 , 2017 Abstract Phenolic resins with different molecular weight were synthesized by the adjustment of phenolic aldehyde, with p-tert-octyl phenol and formaldehyde as materials. Softening point, gel permeation chromatography and 1H NMR Spectroscopy were used to characterize its structure. With the same molar ratio of p-tert-octyl phenol and formaldehyde, a resin with the softening point of 93.1˚C, the mean molecular weight of 1050 and relatively concentrated distribution of molecular weight was made. Results indicate that the expected molecular weight, molecular weight distribution and structure of resin can be made by the control of molar ratio of p-tert-octyl phenol and formalde- hyde. Keywords Phenolic Resin, Reactive Conditions, Molecular 酚醛比对特辛基苯酚甲醛树脂结构的影响 1 2* 2 2 1 刘雪梅 ，檀俊利 ，林明涛，陈玉平，方 羽 1 中国林科院林产化工研究所南京科技开发总公司，江苏 南京 2 中国林科院林产化学工业研究所，江苏 南京 收稿日期：2017年6月21 日；录用日期：2017年7月8 日；发布日期：2017年7月11 日 *通讯作者。 文章引用: 刘雪梅