AlCrCoFeNiMoTiSi 高熵合金微观组织分析.doc

AlCrCoFeNiMoTiSi 高熵合金微观组织分析 摘要：自从多主元高熵合金出现以来，以它独特的性能突破了传统合金只以一种或两种金属元素为主的设计框架，从而开辟了合金材料世界的新领域。多主元高熵合金是以五种或五种以上主要元素按等摩尔比或近等摩尔比经熔炼、烧结或其他方法组合而成具有金属特性的材料。 本论文选取AI、Cr、Co、Fe、Ni、Mo、Ti、Si八种常用的金属元素，通过改变热处理工艺研究该系列合金的微观组织的变化规律。采用氩气保护真空电弧炉熔炼合金，运用金相显微镜、SEM、XRD等手段对铸态高熵合金进行微观组织的分析。 研究发现：该合金系都形成了简单的BCC、FCC及BCC+FCC结构固溶体，性能具有一定的优越性，热处理工艺对高熵合金的微观组织有着较强的影响，对加强合金耐腐蚀性、耐磨以及硬度起着十分重要的作用，发展应用前景十分广阔。 关键词：高熵合金,微观组织,性能 The microstructure study of AlCrCoFeNiMoTixSiy High-entropy alloys Abstract: Since many main folding Jinyuan high entropy, design framework with its unique performance breaks through the traditional alloy in only one or twokinds of metal elements, thus opening up a new field of alloy material world.Multi principal element high entropy alloy with five or more than five kinds ofmain elements in equimolar ratio or near equimolar ratio by the combination ofmelting, sintering or other methods and has the characteristics of metalmaterials This paper selects AI, Cr, Co, Fe, Ni, Mo, Ti, Si eight kinds of metal elements in common use, variation of the alloy microstructure through heat treatment technology research. Using argon vacuum arc furnace smelting alloy, analyzed by metallographic microscope, SEM, XRD and other means of microstructureof as cast high entropy alloys. The study found: the alloy formation of BCC, FCC and BCC+FCC has the advantages of simple structure solid solution, performance has certain advantages, has a strong influence of heat treatment process on themicrostructure of high entropy alloys, to strengthen the alloy corrosion resistance, wear resistance and hardness plays a very important role in the development, application prospects. Keywords: High-entropy alloys, microstructure, properties 目录 1.绪论 4 1.1概述 4 1.2选题背景、研究的目的和意义 4 1.3本课题研究的主要内容 6 2.文献综述 8 2.1多主元高熵合金的定义 8 2.1.1固溶体混合熵 8 2.1.2高熵合金的界定 9 2.2高熵合金的制备方法 11 2.2.1电弧熔炼+铜模铸造法 11 2.2.2高频感应炉加热熔炼 11 2.2.3其他熔炼方法 12 2.3高熵合金的特点及性能 12 2.4多主元效应 13 2.4.1高熵效应 14 2.4.2 晶格畸变效应 14 2.4.3缓慢扩散效应 15 2.4 鸡尾酒效应 15