低浓度液体酸介质中快速合成sba-15分子筛rapidsynthesisofsba.pdfVIP

2007 年第 65 卷 化 学 学 报 Vol. 65, 2007 第 15 期, 1481～1486 ACTA CHIMICA SINICA No. 15, 1481～1486 ·研究论文· 低浓度液体酸介质中快速合成 SBA-15 分子筛 罗永明a,b 侯昭胤a 郑小明*,a (a 浙江大学西溪校区催化研究所 杭州 310028) (b 昆明理工大学环境科学与工程学院 昆明 650093) 摘要 通过在低浓度无机液体酸介质中添加少量磷钼酸(HPMo), 成功地合成了高度有序的 SBA-15 介孔分子筛. N2 吸 附-脱附、XRD 、TEM 和水热稳定性实验等检测结果表明: 用这种方法不仅可以大幅度降低合成 SBA-15 分子筛所需 液体酸的用量和缩短晶化时间, 同时反应产物 SBA-15 在 100 ℃的水中处理 72 h 后仍然保持六方有序的介孔结构. 关键词 模板剂; 低浓度液体酸; 磷钼酸; SBA-15; 水热稳定性 Rapid Synthesis of SBA-15 Molecular Sieves in Low Concentration Liquid Acid Media LUO, Yong-Minga,b HOU, Zhao-Yina ZHENG, Xiao-Ming*,a a ( Institute of Catalysis, Zhejiang University (Xixi Campus ), Hangzhou 310028) b ( Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650093) Abstract Highly ordered SBA-15 sieves have been successfully synthesized in a low concentration liquid inorganic acid medium via the addition of small amounts of phosphomolybdic acid (HPMo). The solid prod- uct was characterized by N2 adsorption-desorption, XRD, TEM and hydrothermal stability test. These results indicated that small amounts of HPMo in the synthesis media could reduce the amount of liquid inorganic acid and crystallization time greatly. And SBA-15 sieves prepared in this method exhibited an excellent hydrothermal stability, as its hexagonally ordered mesostructure was maintained after