粉煤灰提铝渣中二氧化硅在高浓度碱液中的溶解行为-中冶有色技术网.pdfVIP

第 18 卷专辑 1 中国有色金属学报 2008 年 6 月 Vol.18 Special 1 The Chinese Journal of Nonferrous Metals Jun. 2008 文章编号：1004-0609(2008)S1-0407-05 粉煤灰提铝渣中二氧化硅在高浓度碱液中的溶解行为 吴 艳，翟玉春，牟文宁，孙 扬 (东北大学 材料冶金学院，沈阳 110004) 摘 要：粉煤灰酸法提取氧化铝后渣中二氧化硅含量接近 85%，是制备硅酸钠水玻璃的优质原料。提出了在常压 下用高浓度碱液浸出粉煤灰提铝渣中二氧化硅的工艺；研究了二氧化硅在浓碱体系中的浸出行为。实验结果表明， 在温度为 110 ℃、碱浓度为 50%、液固比为 2.2׃1、时间为 60 min 条件下反应最佳，碱浸渣的 XRD 分析表明， 对酸渣进行二次碱浸后，渣中 SiO2 浸出完全，主要物相为钠硅渣和碳酸盐。 关键词：粉煤灰；渣；浸出；浓碱；硅酸钠；二氧化硅 中图分类号：TQ 110.3 文献标识码：A Dissolving behavior of SiO in residue of fly ash detached Al O in 2 2 3 highly concentrated alkali solution WU Yan, ZHAI Yu-chun, MU Wen-ning, SUN Yang (School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China) Abstract: The concentration of SiO in the residue of fly ash detached Al O was 85%. It is the excellent material to 2 2 3 prepare Na SiO . A new method of leaching SiO from the residue was studied in atmosphere and highly concentrated 2 3 2 alkali solution. The optimum conditions are: reaction temperature 110 ℃ , alkali concentration 50%, ratio of liquid to ore 2.2׃1 and reaction time 60 min. The XRD was used to analyze the residue after alkali leaching. The result shows that SiO 2 is leached completely and the main phases are Na-Al silicate slime and carbonate. Key words: fly ash; residue; leaching; highly concentrated alkali solutio