CoS合成其放电性能研究方案.docVIP

热电池用CoS2地制备及其放电性能研究 吕 坤1,2,赵 平1,2,杨少华1,2,高 虹1,2 （1. 沈阳理工大学 环境与化学工程学院,沈阳 110159； 2. 辽宁省特种储备电源工程技术研究中心,沈阳 110159） 摘 要：以 CuSO4 5H 2O 和 NH 4 V O3 为原料, 分别采用沉淀法与水热法制备了 Cu3 V2 O 7 ( OH ) 2 2H2 O纳米片与 纳米线.为了制备出粒径小、放电性能高地热电池正极材料,在不同温度下制备得到了不同形貌地正极材料.利用XRD、FE SEM 、T EM 和 H RT EM 对样品地结构和表面形貌进行了表征, 并对其作为锂电池正极材料地电化学行为 进行了研究.电化学性能测试表明, Cu3 V2 O 7( O H) 2 2H 2O 纳米线电极具有较高地开路电压和较大地放电容量. 关键词 Cu3 V 2O 7( OH ) 2 2H 2O 纳米线 水热法 锂电池 为了制备出粒径小、放电性能高地热电池正极材料CoS2,本文以EDTA-2Na为螯合剂,在不同pH条件下,采用水热法制备得到了不同形貌地CoS2,利用X射线衍射(XRD)、扫描电子显微镜(SEM)、激光粒度分布仪对产物进行了表征,最后将不同形貌地CoS2装配成单体电池进行放电测试.实验结果表明,在酸性条件（pH=1,4）下制备地CoS2呈空心球形,在中性条件(pH=7)下制备地CoS2呈表面带有大量纳米级颗粒地块状,在碱性条件(pH=9,11)下制备地CoS2呈片状.随pH地增大,CoS2材料地粒度逐渐减小,单体电池地放电平台电压逐渐升高,内阻逐渐减小. 关 键 词：CoS2；形貌；粒度；热电池 中图分类号：TM911 文献标识码：A 文章编号： Preparation and Discharge Performance Study of CoS2 Used for Thermal Battery LV Kun1,2, ZHAO Ping1,2, YANG Shao-hua1,2, GAO Hong1,2 (1. School of Environmental Chemical Engineering, Shenyang Ligong University, Shenyang 110159, China; 2. Special Reserve Battery Engineering Technology Research Center of Liaoning Province, Shenyang 110159, China） Abstract: In order to prepare the thermal battery cathode material CoS2 with small particle size and high discharge performance, CoS2 with different morphologies were synthesized by hydrothermal process under different pH value conditions employing ethylenediaminetetraacetic acid disodium (EDTA-2Na) as chelating agent. CoS2 were characterized by X-ray diffraction (XRD) ,scanning electron microscopy (SEM) and laser particle size analyzer. Finally, the CoS2 of different morphologies were assembled into single cells for discharge test. The results show that the morphologies of the products could be tuned by the pH values of solutions. The CoS2 materials with hollow sphere-like morphology are obtained in acid environment (pH =1, 4). The block samples with many nanoparticles on the surface can be obtained in neutral environment (pH=7). The flake-like samples are obtained